Hydroxypropyl Methacrylate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Hydroxypropyl Methacrylate?

Hydroxypropyl Methacrylate is a lab-made ester created by combining methacrylic acid with propylene glycol. Chemists first explored it in the 1960s while looking for new plastics that could flex without cracking. Its clear flexible film soon caught the eye of cosmetic formulators who needed lightweight coatings for long-wear products. Today the ingredient is produced through a controlled reaction where methacrylic acid and propylene glycol are mixed under heat with a catalyst then purified to remove leftover acids and water. The result is a stable liquid that blends easily with other cosmetic raw materials. You will most often spot it in nail polishes, lash and brow gels, long-lasting foundations, hair styling products, peel-off masks and some waterproof sunscreens.

Hydroxypropyl Methacrylate’s Cosmetic Benefits/Uses

This ingredient serves one main role in beauty formulas: it is a film former. By creating an invisible flexible layer on skin hair or nails it helps products stick better resist smudging and last longer. The thin film can lock pigments in place give nails a smooth glossy finish or help hold styling agents on hair strands without a heavy feel.

Who Can Use Hydroxypropyl Methacrylate

The light flexible film it forms makes Hydroxypropyl Methacrylate generally suitable for all skin types including oily dry combination and normal skin. Sensitive skin can usually tolerate it because it is not inherently acidic or exfoliating, though anyone with a known acrylic allergy should steer clear since it belongs to the same family of molecules.

The ingredient is synthetic and made without animal by-products so it is considered appropriate for both vegans and vegetarians. No animal testing is needed for its basic production though final products may follow the brand’s individual cruelty free policy.

No research shows that topically applied Hydroxypropyl Methacrylate crosses the skin barrier in amounts that would affect pregnancy or breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should ask a healthcare professional before adding new cosmetic products.

It does not make skin more sensitive to the sun so it is not linked to photosensitivity. Because it forms a breathable film it also will not block the action of daily sunscreen layered on top.

Potential Side Effects/Adverse Reactions

Reactions to Hydroxypropyl Methacrylate vary from person to person. The points below list potential side effects that can occur even though most users will never experience them when the ingredient is used correctly in a finished product.

  • Contact dermatitis marked by redness or itching
  • Allergic rash in individuals sensitized to acrylates
  • Eye irritation if the wet product accidentally enters the eyes before it sets
  • Brittle or weakened nails when overused in nail products without breaks
  • Mild respiratory irritation when filing or removing cured acrylic layers and inhaling dust

If any of these effects occur stop using the product and consult a healthcare professional.

Comedogenic Rating

Hydroxypropyl Methacrylate earns a comedogenic rating of 0 to 1. It is a lightweight synthetic ester that dries into a breathable film on the surface rather than seeping into pores so it has almost no tendency to trap oil or debris. The propylene glycol portion is water loving not oily which further limits pore clogging potential.

This very low score means the ingredient is generally suitable for people who are prone to acne or breakouts.

Finished products typically include it at modest levels alongside non greasy solvents and that keeps any clogging risk minimal.

Summary

Hydroxypropyl Methacrylate performs mainly as a film former creating a clear flexible layer that locks pigments in place boosts wear time resists smudging and leaves nails or hair with a smooth finish. It achieves this by polymerising once applied forming a thin network that clings firmly without feeling heavy.

The ingredient is not especially famous yet its dependable hold gives it a quiet popularity in long wear foundations nail polishes lash and brow gels plus certain sunscreens. Many formulas count on it even if the marketing copy never mentions its name.

Overall it is considered safe for most users with irritation or allergy being rare and usually limited to those already sensitive to acrylates. Still it is wise to run a small patch test whenever you try a new product so you can confirm your skin’s comfort with Hydroxypropyl Methacrylate before full use.

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