Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride?

Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride is a plant-based polymer made from common food starches such as corn or potato. Chemists first oxidize the starch to make it more water loving, then attach small hydroxypropyl groups for flexibility, and finally add a quaternary ammonium salt that carries a positive charge. This last step gives the ingredient its ability to cling to hair and skin surfaces. The process takes place in water-based reactors at moderate temperatures and the finished material is usually spray-dried into a fine powder.

Modified starches started appearing in cosmetics in the late 1990s as brands looked for greener replacements for petroleum-derived polymers. Because this ingredient is biodegradable and sourced from renewable crops it quickly gained traction in rinse-off hair products and has since moved into skin care.

You will now find Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride in shampoos, daily conditioners, deep-treatment masks, leave-in sprays, styling creams, face and body lotions, lightweight moisturizers and even some sunscreens where it helps the formula stay put.

Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride’s Cosmetic Benefits/Uses

This versatile starch derivative improves both the feel and performance of many beauty products.

  • Film forming: Creates a thin flexible layer that locks in moisture, reduces frizz, boosts curl retention and helps pigments or UV filters stay evenly distributed
  • Hair conditioning: The positive charge binds to the negatively charged cuticle making strands smoother, easier to detangle and less prone to breakage
  • Humectant: Attracts and holds water from the surrounding air so formulas stay hydrating and do not dry out on the shelf
  • Skin conditioning: Softens the surface of the skin, giving a silky after-feel without greasiness

Who Can Use Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride

Because it is mild and water soluble, this starch polymer suits almost every skin type including oily, combination, dry and even most sensitive skin. People with known allergies to corn, potato or other source starches should exercise caution as trace proteins might linger after processing.

The ingredient is derived entirely from plant matter and no animal by-products are used during manufacture, making it appropriate for vegans and vegetarians.

Current safety data shows no evidence of systemic absorption or hormonal effects, so products containing Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride are generally viewed as safe for those who are pregnant or breastfeeding. This is not medical advice and anyone who is pregnant or nursing should run all personal care products past a qualified healthcare provider to be safe.

It does not increase photosensitivity so it will not make skin more prone to sunburn. The ingredient is also compatible with common actives such as retinoids and vitamin C and does not interfere with their performance.

Potential Side Effects/Adverse Reactions

Side effects and reactions to the topical application of Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride can vary from person to person. The following is a list of potential issues but they are uncommon when the ingredient is used at typical cosmetic levels.

  • Mild redness or itching on very sensitive skin
  • Contact dermatitis in individuals allergic to source starches
  • Scalp buildup or flaking if high concentrations are left on without rinsing
  • Temporary eye irritation if the product accidentally gets into the eyes

If any negative reaction occurs stop using the product and seek advice from a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5

Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride is water soluble and forms a lightweight breathable film that easily rinses away, so it rarely traps oil or debris inside pores. It lacks the heavy oils and waxes that usually drive up clogging potential, which is why formulators consider it practically non-comedogenic. This makes the ingredient generally suitable for acne-prone or breakout-prone skin. Only in very rich leave-on creams used at high levels could there be a slight risk of buildup.

Summary

Hydroxypropyl Oxidized Starch Pg-Trimonium Chloride is a plant-derived polymer that works as a film former, hair conditioner, humectant and skin conditioner. Its positive charge helps it cling to hair and skin, the starch backbone soaks up water to keep formulas moist and the flexible film smooths strands while locking in surface hydration.

While not as famous as silicone or synthetic styling resins the ingredient has grown popular in eco-minded hair and skin care for delivering silky slip without relying on petroleum sources. You will spot it most in shampoos, conditioners moisturizers and some sunscreens.

Current studies and decades of cosmetic use show a strong safety profile with very low irritation potential. Still, every skin is unique so it is smart to do a quick patch test when trying any new product that contains this or any other active ingredient.

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