Hydroxypropyltrisiloxyl Ipdi/Peg-14 Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 27, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Hydroxypropyltrisiloxyl Ipdi/Peg-14 Copolymer?

Hydroxypropyltrisiloxyl Ipdi/Peg-14 Copolymer is a lab-created ingredient made by linking together two main building blocks: a silicone segment called hydroxypropyltrisiloxyl isophorone diisocyanate and a water-loving chain known as polyethylene glycol-14. When these pieces are bonded the result is a flexible film-forming polymer that balances the silky feel of silicones with the moisture compatibility of PEG. It first appeared in cosmetic chemistry in the early 2000s as formulators searched for lightweight alternatives to heavy silicones that could still boost performance in rinse-off and leave-on products. The process starts with controlled polymerization where the silicone and PEG components react with a diisocyanate linker under strict temperature and pH conditions. The finished material is then purified and supplied either as a clear liquid or a fine powder ready for blending into cosmetic bases. You will most often spot this copolymer in facial cleansers, foaming masks, hydrating gels, light moisturizers, anti-aging serums and even some shampoos or body washes where a smooth skin feel and stable foam are desired.

Hydroxypropyltrisiloxyl Ipdi/Peg-14 Copolymer’s Cosmetic Benefits/Uses

Formulators value this copolymer because it tackles several jobs at once:

  • Binding: Helps hold the recipe together so pigments, oils and actives stay evenly mixed for a consistent texture every time you use the product.
  • Cleansing: Lifts away dirt, oil and makeup without stripping because its silicone portion loosens debris while the PEG segment rinses clean with water.
  • Skin Conditioning: Leaves a thin breathable film that feels silky, reduces roughness and supports a soft after-touch once the product is rinsed or left on.
  • Foam Boosting: Enhances the richness and stability of lather in washes and masks giving users the satisfying cushion of foam often linked to a thorough clean.

Who Can Use Hydroxypropyltrisiloxyl Ipdi/Peg-14 Copolymer

This versatile copolymer is generally well tolerated by all skin types including dry skin that appreciates the light conditioning film, oily or acne-prone skin that benefits from the non-occlusive feel and normal or combination skin that simply enjoys a smoother cleanse. Sensitive skin users usually do fine too because the molecule is large and non-reactive, though anyone with a known silicone sensitivity should proceed with caution.

The material is fully synthetic and contains no animal-derived components so it suits both vegetarians and vegans. It has not been linked to endocrine concerns and does not interfere with common pregnancy-related skin changes, making it acceptable for use during pregnancy and while breastfeeding; however this is not medical advice and expectant or nursing mothers should always check with their physician before starting any new product.

The copolymer does not increase photosensitivity so there is no added need for extra sun protection beyond normal daily SPF practices. It also plays well with common actives like niacinamide, vitamin C and gentle exfoliating acids without destabilising them.

Potential Side Effects/Adverse Reactions

Reactions to topical Hydroxypropyltrisiloxyl Ipdi/Peg-14 Copolymer differ from person to person. The points below outline potential issues only, and most users will not encounter them when the ingredient is formulated and used correctly.

  • Mild transient redness
  • Temporary stinging if applied on broken or freshly exfoliated skin
  • Rare silicone-related sensitivity presenting as itching or small bumps
  • Eye irritation if a foaming cleanser containing the ingredient is rubbed directly into the eyes

If any irritation or discomfort persists stop using the product and seek advice from a qualified healthcare professional.

Comedogenic Rating

Rating: 1/5 (very low)

Hydroxypropyltrisiloxyl Ipdi/Peg-14 Copolymer forms a breathable lightweight film that lets sebum and sweat escape instead of trapping them in pores. Its bulky structure keeps it on the surface so it rarely works its way into follicles and the PEG portion helps it rinse off cleanly in wash-off products which limits buildup.

Thanks to this low occlusive profile the ingredient is generally considered suitable for skin that is prone to acne or frequent breakouts.

If a formula also contains heavy oils or waxes overall pore-clogging potential will depend on those other components so assess the product as a whole.

Summary

Hydroxypropyltrisiloxyl Ipdi/Peg-14 Copolymer binds water and oil phases so textures stay uniform, lifts away dirt during cleansing, deposits a silky conditioning veil and boosts foam for a richer lather. It pulls this off by marrying a slick silicone backbone with a water friendly PEG chain which spreads smoothly then rinses without residue.

The copolymer is not yet a buzzword ingredient yet its appearance is steadily growing in cleansers masks and lightweight moisturizers where brands want a soft touch minus greasiness.

Regulatory reviews place it in the low risk category with only infrequent irritation reports making it broadly safe for daily use. Still, it is smart skincare practice to patch test any new product containing this or any other unfamiliar ingredient just to be sure your skin stays happy.

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