Jojoba Oil/Wax Polyglyceryl-3 Esters: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Jojoba Oil/Wax Polyglyceryl-3 Esters?

Jojoba Oil/Wax Polyglyceryl-3 Esters is a plant-derived ingredient made from jojoba seeds. Chemically, it links jojoba oil and jojoba wax to a small chain of three glycerin units called polyglycerin-3. The result is an oil-like substance that mixes better with water than plain jojoba oil, giving formulators a flexible, easy-to-use material.

Jojoba itself has been valued since the 1970s as a sustainable stand-in for sperm whale oil. Over time chemists looked for ways to boost its performance and discovered that joining it with polyglycerin improved spreadability and rinsing. This ester is produced through transesterification, a controlled heating process that swaps parts of the fatty acids on jojoba oil and wax with polyglycerin-3. The outcome keeps the skin-loving traits of jojoba while adding a light, silky feel.

You will find Jojoba Oil/Wax Polyglyceryl-3 Esters in rinse-off and leave-on hair conditioners, masks, styling creams, color-protection formulas and even beard balms. Its mild nature also makes it popular in sensitive-scalp treatments and kid-friendly products.

Jojoba Oil/Wax Polyglyceryl-3 Esters’s Cosmetic Benefits/Uses

Its main job in cosmetics is hair conditioning. The ester coats each strand in a thin, non-greasy layer that smooths cuticles, reduces frizz and makes detangling easier. Because it has both oily and water-loving parts, it helps lock in moisture without leaving heavy buildup, so hair feels soft, light and more manageable.

Who Can Use Jojoba Oil/Wax Polyglyceryl-3 Esters

This ingredient is generally well tolerated by all skin and scalp types including dry, normal, combination, oily and sensitive. Its lightweight film forms without leaving a greasy residue so even fine, easily weighed down hair usually fares well. No skin type is specifically flagged as incompatible, though anyone with a known allergy to jojoba should steer clear.

Because it is sourced entirely from jojoba plants and no animal-derived materials are involved at any step, it suits both vegans and vegetarians looking for cruelty-free hair care options.

No studies have linked Jojoba Oil/Wax Polyglyceryl-3 Esters to problems in pregnancy or while nursing. That said this is not medical advice and anyone who is pregnant or breastfeeding should show any cosmetic product to a qualified doctor before regular use.

The ester does not increase photosensitivity so sun exposure precautions are not necessary beyond normal everyday protection. It is also color safe, making it appropriate for chemically treated or dyed hair.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Jojoba Oil/Wax Polyglyceryl-3 Esters vary from person to person. The following list covers potential reactions only and most users will not experience them when the ingredient is properly formulated and applied.

  • Mild contact irritation such as redness or itchiness on very sensitive skin
  • Allergic response in individuals already sensitized to jojoba derivatives
  • Folliculitis or scalp breakouts in rare cases where heavy layering leads to product buildup
  • Stinging or watering of the eyes if the product accidentally drips into them

If any of these effects occur stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 out of 5. The esterified form of jojoba has a lighter, more water-friendly structure than straight jojoba oil, so it sits on the surface without readily sinking into pores. This makes it very unlikely to clog follicles even on oily skin. Overall the ingredient is considered safe for people prone to acne or breakouts. Since it is used mainly in rinse-off or lightweight leave-on hair products, the chance of pore congestion on nearby facial skin is even lower.

Summary

Jojoba Oil/Wax Polyglyceryl-3 Esters is a plant-derived hair conditioner that smooths cuticles, tames frizz and boosts softness by forming a thin breathable film that blends oil-loving jojoba chains with water-loving glycerin units. Its dual nature helps it rinse clean while still locking in moisture so hair stays light and manageable.

The ester is popular with formulators looking for vegan sustainable substitutes for silicone or mineral oil, though it remains more of a specialty ingredient than a household name. Most users tolerate it well and safety data show a low risk of irritation or sensitization. As with any new cosmetic, patch testing a small area first is a smart way to rule out personal reactions before regular use.

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