Magnesium Ascorbyl Phosphate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Magnesium Ascorbyl Phosphate?

Magnesium Ascorbyl Phosphate, often shortened to MAP, is a stable form of vitamin C created by binding ascorbic acid to phosphoric acid and then pairing the result with magnesium. This tweak keeps vitamin C from breaking down quickly when exposed to air, heat or light. MAP first appeared in skincare research during the late 1980s as chemists searched for a gentler vitamin C that would stay effective longer in water-based formulas. Today the ingredient is produced in a lab by combining purified ascorbic acid with phosphorus compounds, adjusting the pH, adding magnesium salts then filtering and drying the mixture into a fine white powder.

Its stability and water solubility make MAP easy to add to many product types. You will find it in lightweight serums, daily moisturizers, brightening creams, sheet masks, eye treatments and anti-aging products that target dullness or early lines.

Magnesium Ascorbyl Phosphate’s Cosmetic Benefits/Uses

This ingredient brings two main perks to a formula

  • Antioxidant – MAP helps neutralize free radicals created by UV rays and pollution. By cutting down this oxidative stress it supports a fresher brighter look and can slow the appearance of fine lines
  • Skin Conditioning – It encourages smoother softer skin by supporting collagen production and improving moisture retention which can leave the complexion looking plump and even-toned

Who Can Use Magnesium Ascorbyl Phosphate

MAP is generally well tolerated by all skin types including dry, normal, combination and oily skin. Because it has a neutral pH and is less acidic than pure vitamin C it tends to be gentler on sensitive or redness-prone skin while still offering brightening benefits. Extremely reactive or barrier-compromised skin may wish to start with lower concentrations to be sure it feels comfortable.

The ingredient is made synthetically in a lab using vitamin C, phosphorus compounds and magnesium salts so no animal-derived materials are required. For that reason products featuring MAP are usually suitable for vegans and vegetarians, though it is still wise to double-check that the full formula and manufacturing process are cruelty-free.

Current research shows no specific concerns for topical magnesium ascorbyl phosphate during pregnancy or while breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should show the full ingredient list to their doctor before adding a new product just to be safe.

Unlike some exfoliating acids MAP does not make skin more sensitive to the sun. It may even provide a small protective boost through its antioxidant activity, yet daily sunscreen is still essential for overall skin health.

MAP layers well with most other actives, including niacinamide and hyaluronic acid, and it can be used morning or night depending on personal routine.

Potential Side Effects/Adverse Reactions

Responses to topical magnesium ascorbyl phosphate vary from person to person. The points below list potential side effects and interactions that have been reported, but they remain uncommon when the ingredient is formulated and used correctly.

  • Mild tingling or stinging on first application
  • Transient redness or warmth, especially on very sensitive skin
  • Dry or tight feeling if used in a very high concentration without enough moisture in the rest of the routine
  • Rare allergic contact dermatitis resulting in rash or itching
  • Potential interaction with highly acidic products that may lead to slight instability or decreased effectiveness rather than harm

If any irritation or unusual reaction occurs discontinue use and seek advice from a qualified healthcare professional or dermatologist.

Comedogenic Rating

Rating: 0 / 5 (non-comedogenic)

Magnesium Ascorbyl Phosphate is water soluble, lightweight and does not leave an oily film on the skin, all factors that keep pores clear. It does not contain fatty acids or heavy emollients that can clog follicles, and studies show no link between MAP and increased comedone formation.

Suitable for acne-prone or breakout-prone skin.

Because MAP is usually delivered in oil-free or low-oil formulas such as serums and gels, the finished product often remains non-comedogenic as well, but always check the full ingredient list since other components could change the overall pore-clogging potential.

Summary

Magnesium Ascorbyl Phosphate provides antioxidant protection, boosts collagen synthesis and improves moisture retention, resulting in brighter smoother skin. It accomplishes this by donating vitamin C activity in a form that stays stable in water-based products and at a skin-friendly pH.

While not as universally known as classic vitamin C or niacinamide, MAP is gaining popularity for people who want the glow of vitamin C without the sting or quick oxidation.

Overall safety data are strong. Adverse reactions are rare and usually mild, making it a low-risk addition to most routines. As with any new skincare ingredient, patch testing a small area first is wise to rule out individual sensitivities.

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