Methoxy Peg-23 Methacrylate/Glyceryl Diisostearate Methacrylate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Methoxy Peg-23 Methacrylate/Glyceryl Diisostearate Methacrylate Copolymer?

Methoxy Peg-23 Methacrylate/Glyceryl Diisostearate Methacrylate Copolymer is a man-made ingredient created by linking two smaller building blocks called methacrylate monomers. One of these building blocks carries a methoxy-capped PEG chain with 23 units, while the other is based on glyceryl diisostearate, a fatty substance that comes from plant oils such as coconut or palm. Chemists combine these monomers through a controlled reaction known as polymerization, turning them into a larger, stable molecule that forms thin flexible films on skin.

The use of acrylic-type polymers in beauty items dates back to the 1970s when formulators looked for lightweight film formers to replace heavier waxes. Over time the technology improved, leading to specialized copolymers like this one that blend water-loving PEG segments with oil-loving fatty chains. The balance gives brands an easy way to add a smooth protective layer without a greasy feel.

During production, the monomers are mixed in a solvent, a catalyst starts the reaction, then the solvent is removed and the finished polymer is purified and dried. The result is a fine powder or viscous liquid that dissolves or swells in the oil phase of a formula.

You will most often find Methoxy Peg-23 Methacrylate/Glyceryl Diisostearate Methacrylate Copolymer in moisturizers, leave-on masks, daily lotions, lightweight sunscreens, BB creams and anti-aging serums where it helps create a soft even finish and locks in moisture.

Methoxy Peg-23 Methacrylate/Glyceryl Diisostearate Methacrylate Copolymer’s Cosmetic Benefits/Uses

In skin care this copolymer mainly serves one purpose that brings several visible perks.

As a skin protecting agent it forms an invisible breathable film that shields the surface from harsh weather, airborne dirt and water loss. This film smooths rough patches, boosts softness and helps active ingredients stay in place longer so the product can work more effectively.

Who Can Use Methoxy Peg-23 Methacrylate/Glyceryl Diisostearate Methacrylate Copolymer

This film forming polymer suits most skin types including dry, normal, combination and even sensitive skin because it is non reactive and lightweight. Oily and acne prone users can also tolerate it well since it creates a breathable barrier rather than a heavy wax however very clog prone individuals who struggle with any rich emollients may prefer a patch of caution if a formula pairs the copolymer with lots of additional oils.

The building blocks are either synthetic or plant derived so the ingredient is typically suitable for vegans and vegetarians. Some manufacturers still source stearic acid from animal fats so strict vegans may want to confirm the supply chain with the brand.

No data indicate a risk for pregnant or breastfeeding women when the polymer is applied to intact skin since its large molecular size keeps it on the surface. This content is not medical advice; anyone who is expecting or nursing should check with a healthcare professional before adding new products just to be safe.

The copolymer is not known to cause photosensitivity and does not make skin more vulnerable to sunburn. It is stable across a wide pH range and plays nicely with common skincare actives so there are no special usage rules beyond normal sunscreen during daytime.

Potential Side Effects/Adverse Reactions

Reactions to topical Methoxy Peg-23 Methacrylate/Glyceryl Diisostearate Methacrylate Copolymer vary from person to person. The following is a list of potential side effects only; most users will not experience them when the ingredient is properly formulated and used as directed.

  • Mild skin irritation such as transient redness or stinging on very sensitive skin
  • Allergic contact dermatitis in rare cases for individuals with an acrylic or methacrylate allergy
  • Temporary clogged pores if used in a very heavy formula on skin already prone to congestion
  • Eye irritation if the product accidentally gets into the eyes

If any discomfort, redness or other negative reaction occurs discontinue use and seek medical advice if symptoms persist or worsen.

Comedogenic Rating

Rating: 1 out of 5

This polymer sits mostly on the surface and forms a thin breathable film rather than sinking into pores. Its large molecular size plus the balance of water-loving PEG segments and lightweight fatty chains means it is far less likely to clog pores than heavier waxes or butters. For most people the risk of breakouts is low, so the ingredient is generally considered suitable for acne-prone skin.

Keep in mind that the final formula matters. If the copolymer is blended with rich oils or silicones the overall product could feel heavier and raise the pore-clogging potential.

Summary

Methoxy Peg-23 Methacrylate/Glyceryl Diisostearate Methacrylate Copolymer works mainly as a skin-protecting film former. It spreads into an invisible layer that locks in moisture, smooths texture, shields against pollution and helps actives stay put. Because it combines water-friendly PEG chains with soft fatty branches it delivers this protection without a greasy finish.

The ingredient is not a household name like hyaluronic acid yet formulators appreciate its lightweight feel so you will spot it in a growing number of moisturizers, sunscreens and BB creams.

Current safety data show it is well tolerated with a very low risk of irritation or pore clogging when used as directed. Still, skin can react differently so it is always smart to patch test any new product before applying it to your whole face.

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