Methyl Caprylate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Methyl Caprylate?

Methyl caprylate, also known as methyl octanoate, is an ester created when caprylic acid is joined with methanol. Caprylic acid is a naturally occurring fatty acid found in coconut oil and palm kernel oil, and manufacturers can either isolate it from these plant sources or produce it synthetically. When caprylic acid reacts with methanol under heat and the presence of an acid catalyst, methyl caprylate forms as a clear, lightweight liquid with a faint, fruity scent.

Perfumers first took interest in this ingredient in the early 1900s because of its pleasant aroma and smooth feel on skin. Over time formulators realized that methyl caprylate could do more than scent a product, leading to its wider use in skin care and personal care items throughout the late twentieth century.

Today large-scale production typically relies on a controlled esterification process, followed by purification steps like distillation to remove residual alcohol or acid. The result is a stable ingredient that blends easily with oils, silicones and many common cosmetic bases.

You will most often spot methyl caprylate in moisturizers, body lotions, facial oils, sunscreens, hair conditioners, bath oils, fragrance mists, sheet masks and lightweight serums where a silky finish or subtle scent is desired.

Methyl Caprylate’s Cosmetic Benefits/Uses

This multitasker brings three main benefits to a formula

  • Perfuming – Its delicate fruity note helps mask less pleasant raw material odors and adds a soft finishing scent, allowing brands to reduce or simplify added fragrance blends
  • Skin Conditioning – By forming a light, breathable film on the surface it leaves skin feeling smoother and more supple, which can enhance overall product feel and user satisfaction
  • Emollient – As a small-molecule oil it fills the gaps between skin cells, softening dryness and improving flexibility without a greasy residue

Who Can Use Methyl Caprylate

Methyl caprylate’s lightweight texture suits most skin types. Normal, dry and combination skin usually welcome the quick-absorbing emollience, while oily skin tends to tolerate it because it is less greasy than heavier plant oils. Very acne-prone skin may want to monitor use since any oil-derived ingredient can potentially add to pore congestion for some individuals.

The ingredient is either plant-sourced from coconut or palm kernel oil or produced synthetically, so it fits vegan and vegetarian lifestyles when the finished formula is confirmed cruelty-free.

Current safety data show no known reproductive or developmental concerns at the tiny concentrations used in cosmetics, so products with methyl caprylate are generally considered safe for pregnant or breastfeeding women. This is not medical advice; anyone who is expecting or nursing should review their skincare routine with a qualified health professional.

Methyl caprylate is not known to cause photosensitivity, so it will not make skin more prone to sunburn. It also plays well with common actives like vitamin C, niacinamide and retinoids, making it a flexible add-on in multi-step routines.

Potential Side Effects/Adverse Reactions

Individual reactions to topical methyl caprylate differ from person to person. The points below list potential, though uncommon, side effects. Assuming the ingredient is properly formulated most users will not encounter these issues.

  • Mild skin irritation such as redness or stinging, especially on compromised or highly sensitive skin
  • Allergic contact dermatitis in those with an established fragrance or ester allergy
  • Temporary acne flare-ups in very oily or congestion-prone skin
  • Eye irritation if the product migrates into the ocular area

If any of these reactions occur discontinue use and seek advice from a healthcare professional if symptoms persist.

Comedogenic Rating

Rating: 2 out of 5

Methyl caprylate is a light ester with a smaller molecular size than many plant oils, allowing it to spread quickly and absorb rather than sit heavily on the surface. That keeps its pore-clogging potential fairly low, yet the fact that it is still derived from a fatty acid gives it a small chance of contributing to build-up on very reactive or severely oily skin types. Most users with normal, dry or combination skin experience no breakout issues.

Overall it can be considered suitable for people prone to acne or breakouts, provided the rest of the formula is also low in comedogenic ingredients.

Keep in mind concentration and product format matter; a light serum with a few percent methyl caprylate behaves differently from a thick balm rich in the same ester.

Summary

Methyl caprylate mainly acts as a perfume ingredient, skin conditioner and emollient. Its small ester molecules slip between skin cells to soften and smooth while leaving behind a subtle fruity scent that masks less pleasant raw material odors. Because it is lightweight and compatible with a wide range of bases it lends a silky, non-greasy feel to lotions, sunscreens, serums and hair care.

Although it is not a headline grabbing all-star like hyaluronic acid or retinol, formulators appreciate methyl caprylate for the quiet work it does behind the scenes, so it shows up in many everyday products without taking center stage.

Current safety assessments rank it as low risk for irritation or systemic toxicity at the tiny levels used in cosmetics. Still, skin can be unpredictable so it is wise to patch test any new product that contains methyl caprylate before applying it to a larger area.

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