Peg-10 Acrylate Dipentaerythrityl Pentaacrylate/Hdi Crosspolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-10 Acrylate Dipentaerythrityl Pentaacrylate/Hdi Crosspolymer?

PEG-10 Acrylate Dipentaerythrityl Pentaacrylate/HDI Crosspolymer is a synthetic ingredient created in the lab rather than harvested from plants or animals. Chemists start with dipentaerythrityl pentaacrylate, a molecule that has several acrylate groups ready to link up, and combine it with hexamethylene diisocyanate (HDI). These two react to form a three-dimensional network, known as a crosslinked polymer. To improve the polymer’s feel and flexibility, it is “capped” with PEG-10 acrylate, a short chain of polyethylene glycol. The result is a lightweight, durable material that can spread smoothly when applied to nails or skin.

The use of crosslinked acrylate polymers in cosmetics dates back to the late 20th century, when formulators looked for ways to add strength and shine to nail products without relying solely on resins or nitrocellulose. As safety data grew and manufacturing methods became more efficient, this particular polymer earned a place in professional and over-the-counter nail treatments.

Production happens in controlled reactors where temperature and pH are carefully monitored to make sure the polymer forms evenly. Once the reaction is complete, the material is purified, ground into a fine powder or dispersed in liquid, then blended into cosmetic formulas.

You will most often find PEG-10 Acrylate Dipentaerythrityl Pentaacrylate/HDI Crosspolymer in nail polishes, base coats, top coats and strengthening treatments. Its film-forming properties can also be useful in certain long-wear makeup products such as liquid eyeliners, although nail care is its primary home.

Peg-10 Acrylate Dipentaerythrityl Pentaacrylate/Hdi Crosspolymer’s Cosmetic Benefits/Uses

In cosmetic formulas this ingredient serves one clear purpose that delivers several user-friendly perks.

Nail conditioning: The polymer forms a smooth, flexible film over the nail surface. This film helps protect against chips, peeling and environmental stress while giving the nail a glossy, even finish. Because the film is lightweight, it does not feel heavy or overly stiff, letting the natural nail flex without cracking the polish. The result is longer-lasting manicures, improved shine and a healthier-looking nail plate.

Who Can Use Peg-10 Acrylate Dipentaerythrityl Pentaacrylate/Hdi Crosspolymer

Because this polymer sits on the surface rather than penetrating deeply it is generally considered suitable for all skin types, including dry, oily and sensitive. People with very reactive or allergy-prone skin should still keep an eye on the full ingredient list of any product, as irritation usually comes from accompanying solvents or pigments rather than the polymer itself.

The material is produced entirely from synthetic raw materials with no animal by-products so it is appropriate for vegans and vegetarians.

There is no specific research linking this ingredient to problems during pregnancy or breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should run any cosmetic product past a healthcare professional just to be safe.

The polymer does not increase photosensitivity and has no known interactions with sunlight. As with any nail or makeup ingredient it should be applied to clean intact skin or nails to avoid trapping bacteria underneath the film.

Potential Side Effects/Adverse Reactions

Reactions to topical Peg-10 Acrylate Dipentaerythrityl Pentaacrylate/Hdi Crosspolymer vary from person to person. The points below list potential side effects but most users will not experience them when the ingredient is properly formulated and used.

  • Mild skin or cuticle irritation
  • Redness around the nail fold
  • Contact dermatitis in individuals already sensitized to acrylates or isocyanates
  • Brittle nails if the product is removed too aggressively or too often

If any of these effects occur discontinue use and consult a healthcare professional.

Comedogenic Rating

Rating: 0/5 (non-comedogenic)

This ingredient is a large crosslinked polymer that stays on top of the skin or nail and is not oily or waxy. Because it cannot slip into pores or mix with sebum it is very unlikely to clog pores or spark breakouts.

Suitable for acne-prone and breakout-prone users.

No studies suggest it worsens blackheads or whiteheads even in leave-on formulas, but other ingredients in the same product, such as heavy oils or fragrances, could still cause issues.

Summary

PEG-10 Acrylate Dipentaerythrityl Pentaacrylate/HDI Crosspolymer is used mainly as a nail-conditioning film former. It spreads into a thin flexible layer that boosts shine, guards against chips and lets the natural nail bend without cracking. By sitting on the surface it adds gloss and strength while keeping the feel light.

It is popular with formulators of nail polish, base coats and top coats though it remains a niche ingredient outside that category. Safety reviews rate it as low risk with only rare irritation in people already sensitive to acrylates or isocyanates.

Overall it is considered safe for most users and all skin types. As with any new product a quick patch test is a smart step before regular use.

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