Peg-20 Methyl Glucose Distearate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-20 Methyl Glucose Distearate?

Peg-20 Methyl Glucose Distearate is a plant-derived ingredient created by reacting glucose from corn with stearic acid from vegetable oils, then attaching about twenty units of ethylene oxide. The result is a waxy, off-white substance that disperses easily in water and oil. First introduced in the late 1980s as a gentle alternative to harsh detergents, it quickly became popular for its ability to stabilize lotions without leaving a greasy feel. Production starts with methyl glucose obtained from starch, which is esterified with stearic acid to form methyl glucose distearate. This base is then polyethylene glycolated, giving the final material its “Peg-20” rating that reflects the average number of ethylene oxide units. You will most often find it in daily moisturizers, face masks, creamy cleansers, sunscreens, hair conditioners, anti-aging creams and baby care formulas where a smooth, silky texture is desired.

Peg-20 Methyl Glucose Distearate’s Cosmetic Benefits/Uses

Formulators rely on this multitasker for the following reasons:

  • Emulsifying: It helps oil and water mix uniformly, creating stable creams and lotions that do not separate. This improves product shelf life and ensures each application delivers consistent performance
  • Emollient: It softens and smooths skin or hair by forming a light, breathable layer that reduces moisture loss, leaving the surface feeling velvety without heaviness

Who Can Use Peg-20 Methyl Glucose Distearate

This ingredient suits most skin types, including dry, normal, combination, oily and even sensitive skin, because it is mild and non-pore-clogging in the low amounts typically used. Those with extremely acne-prone skin may still prefer lighter formulas overall, but Peg-20 Methyl Glucose Distearate itself is not considered comedogenic.

It is generally appropriate for vegans and vegetarians since the glucose comes from corn and the stearic acid is usually sourced from vegetable oils. Anyone following a strict plant-based lifestyle should still check with the brand to confirm no animal-derived feedstocks were used in a specific batch.

No data show harm for women who are pregnant or breastfeeding when this ingredient is applied topically in cosmetic concentrations. This is not medical advice; expectant or nursing mothers should review any skincare product with their physician to be on the safe side.

Peg-20 Methyl Glucose Distearate does not cause photosensitivity, so it will not make skin more prone to sunburn. It is also fragrance-free and gluten-free which may interest people avoiding those components.

Potential Side Effects/Adverse Reactions

Reactions to topical Peg-20 Methyl Glucose Distearate differ from person to person. The issues listed below are only potential side effects and are unlikely for the average user when the ingredient is properly formulated.

  • Irritation or transient redness in very sensitive skin when used at high concentrations
  • Allergic contact dermatitis in individuals already sensitized to polyethylene glycols or fatty acid esters
  • Eye stinging or watering if a cleanser or cream accidentally gets into the eyes
  • Mild acne flare-up for those highly prone to breakouts if the overall product is heavy or occlusive

If any negative reaction occurs stop using the product immediately and consult a healthcare professional for further guidance.

Comedogenic Rating

Rating: 1 / 5

Peg-20 Methyl Glucose Distearate scores a low 1 because its large, water-loving PEG chains stop the fatty parts from packing tightly on skin, so pores are less likely to get blocked. It tends to sit lightly on the surface then rinse or wear off without leaving a thick film.

In short it is generally fine for people who break out easily, provided the rest of the formula is also lightweight.

Keep in mind that very high percentages or pairing it with heavy oils can raise the overall comedogenic feel of a product even if this single ingredient stays mild.

Summary

Peg-20 Methyl Glucose Distearate works mainly as an emulsifier and emollient. Its sugar-based head loves water while its twin stearic tails love oil, so it bridges the two phases and locks them together into a smooth stable cream. The same structure leaves a soft flexible layer on skin or hair that cuts transepidermal water loss and boosts slip without greasiness.

It is a fairly common pick in moisturizers, cleansers and hair care since it is plant-derived, easy to work with and gives a silky feel that shoppers enjoy, though it is not as famous as ingredients like glycerin or shea butter.

Safety data rate it as low risk with irritation or allergy being rare. Still, everyone’s skin is different so do a quick patch test before fully adding a new product that contains it.

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