Peg-20 Sorbitan Isostearate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-20 Sorbitan Isostearate?

Peg-20 Sorbitan Isostearate is a plant-derived liquid surfactant made by linking sorbitan (a sugar alcohol obtained from corn or other starchy crops) with isostearic acid (a branched fatty acid often sourced from vegetable oils) and then attaching about twenty units of ethylene oxide. The result is a partly water-loving and partly oil-loving molecule that helps oil and water mix smoothly.

Chemists first explored sorbitan esters in the 1940s when the food and textile industries needed safe mild emulsifiers. As cosmetic formulas became more sophisticated in the 1970s and 1980s, manufacturers adopted ethoxylated sorbitan esters such as Peg-20 Sorbitan Isostearate for their mildness, versatility and stability in a wide pH range.

Production starts with sorbitol, which is dehydrated to sorbitan, then esterified with isostearic acid. The ester is next reacted with ethylene oxide in a controlled setting to graft on the polyethylene glycol (PEG) chain. Each step is carefully purified to remove free fatty acids and unreacted ethylene oxide, yielding a clear viscous liquid.

You will most often find Peg-20 Sorbitan Isostearate in facial cleansers, micellar waters, make-up removers, sheet mask essences, lightweight lotions, sunscreens, fragrance solubilizers and some hair conditioners where it helps keep oils fragrances and silicones evenly dispersed.

Peg-20 Sorbitan Isostearate’s Cosmetic Benefits/Uses

This ingredient serves two key roles that improve the feel and performance of many formulas

  • Cleansing: Its surfactant nature lifts away dirt, excess oil and makeup without stripping skin, leaving a soft refreshed after-feel that suits daily-use cleansers and micellar waters
  • Emulsifying: Its balanced water-and-oil affinity stabilizes oil-in-water emulsions so creams and lotions stay smooth resist separation and deliver an even dose of active ingredients with every use

Who Can Use Peg-20 Sorbitan Isostearate

Peg-20 Sorbitan Isostearate is considered gentle enough for most skin types, including normal, dry, oily and combination. Its mild nature and low risk of clogging pores make it suitable for those who struggle with sensitivity or acne, while the light non-greasy feel works well for oily complexions. People with very compromised or broken skin might notice a slight sting because surfactants can slip into tiny cracks, so extra care is wise in that case.

The ingredient is typically sourced from plant-based raw materials and contains no animal-derived components, so it is suitable for vegans and vegetarians. Always check the full product label in case other ingredients differ.

No data suggest that Peg-20 Sorbitan Isostearate poses a special risk to women who are pregnant or breastfeeding when used in rinse-off or leave-on cosmetics. This is not medical advice and anyone who is pregnant or nursing should run all skincare products past a doctor just to be safe.

The molecule itself does not increase photosensitivity, so it will not make skin more prone to sunburn. Standard daily sun protection is still important for overall skin health.

Potential Side Effects/Adverse Reactions

Reactions to Peg-20 Sorbitan Isostearate can vary from person to person. The following points outline potential side effects, but they are uncommon when the ingredient is used at normal cosmetic levels.

  • Mild skin irritation, especially on very sensitive or damaged skin
  • Stinging or redness if the product is left on wounded or freshly exfoliated areas
  • Rare cases of allergic contact dermatitis involving itching, rash or swelling
  • Eye irritation with tearing or burning if the product accidentally gets into the eyes
  • Theoretical risk of irritation from trace residues of ethylene oxide or 1,4-dioxane, which reputable manufacturers minimize through purification

If any irritation, itching or other adverse reaction occurs discontinue use and consult a healthcare professional.

Comedogenic Rating

Rating: 1 / 5

Peg-20 Sorbitan Isostearate is mainly a cleansing and emulsifying agent, not a heavy oil or wax. Its molecules are water soluble and rinse away easily so they are unlikely to build up inside pores. For that reason it earns a low comedogenic score of 1.

Suitable for acne prone or breakout prone skin because the risk of clogged pores is minimal.

Keep in mind that the finished product formula and how often it is used can affect pore clogging more than any single ingredient.

Summary

Peg-20 Sorbitan Isostearate acts as a mild surfactant that lifts away dirt and makeup while also serving as an emulsifier that keeps oil and water mixed so creams stay smooth. It pulls this off by having one end that likes water and another that likes oil allowing it to sit at the boundary and hold the two together.

It is not the flashiest ingredient but formulators reach for it often in micellar waters gentle cleansers sunscreens and light lotions because it is dependable affordable and plant derived.

Safety studies and long use history show it is generally low risk with irritation or allergy being rare. Still every skin is different so doing a quick patch test with any new product is a smart habit.

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