Peg-20 Tallow Ammonium Ethosulfate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-20 Tallow Ammonium Ethosulfate?

Peg-20 Tallow Ammonium Ethosulfate is a conditioning agent made from animal-derived tallow fatty acids that have been linked to about twenty units of ethylene oxide, then converted into a quaternary ammonium salt. The result is a water-loving, positively charged ingredient that can cling to negatively charged surfaces like hair and skin. Quaternary ammonium compounds first appeared in personal care products in the 1950s when formulators looked for gentler alternatives to harsh soaps. Peg-20 Tallow Ammonium Ethosulfate gained popularity as a versatile antistatic and softening additive during the growth of modern hair conditioning products in the 1980s.

Manufacturing starts by collecting fatty acids from rendered tallow, reacting them with ethylene oxide to create a polyethylene glycol (PEG) chain of roughly twenty units, then introducing a sulfate group followed by neutralization with ammonia. This sequence yields a liquid or paste that dissolves easily in water and blends well with other ingredients.

You will most often see Peg-20 Tallow Ammonium Ethosulfate in rinse-off and leave-in hair conditioners, shampoos aimed at reducing static, detangling sprays, anti frizz serums, styling creams and some body lotions where a lightweight conditioning feel is desired.

Peg-20 Tallow Ammonium Ethosulfate’s Cosmetic Benefits/Uses

The primary role of Peg-20 Tallow Ammonium Ethosulfate in cosmetics is as an antistatic agent. By depositing a thin, positively charged layer on hair or skin it helps neutralize static electricity that can cause flyaways or a rough feel. This makes hair easier to comb, improves smoothness and adds a soft touch without weighing strands down.

Who Can Use Peg-20 Tallow Ammonium Ethosulfate

This ingredient is generally considered safe for all skin and hair types. Its antistatic action benefits fine, thick, straight or curly hair without leaving a heavy coating, and its mild nature makes it suitable for normal, dry or oily skin on the scalp and body. People with very sensitive skin should still monitor how their skin feels, as with any new cosmetic ingredient.

Peg-20 Tallow Ammonium Ethosulfate is derived from animal fat, so it is not appropriate for vegans or strict vegetarians. Those who prefer plant based or synthetic alternatives may want to check product labels for this detail.

Available safety data show no specific risks for women who are pregnant or breastfeeding when the ingredient is used in rinse off or leave in hair products. This is not medical advice, and anyone who is pregnant or nursing should discuss any cosmetic product with a healthcare professional before adding it to a routine.

The ingredient does not make skin more sensitive to sunlight, so it is not considered photosensitizing. It also has no known effects on hair color, chemical relaxers or other common hair treatments.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Peg-20 Tallow Ammonium Ethosulfate can vary from person to person. The issues listed below are possible but uncommon when the ingredient is used at the levels typically found in cosmetic formulas.

  • Skin irritation such as mild redness or itching in people with very sensitive skin
  • Allergic contact dermatitis in rare cases where an individual is sensitive to quaternary ammonium compounds or residual tallow proteins
  • Eye irritation if the product accidentally gets into the eyes
  • Buildup or a heavy feel on hair when used in high concentrations or not rinsed thoroughly

If any of these reactions occur, discontinue use and consult a healthcare professional for further advice.

Comedogenic Rating

Rating: 1 out of 5. Peg-20 Tallow Ammonium Ethosulfate is highly water soluble and tends to rinse clean, so it does not stay on skin long enough to clog pores. Its molecular structure is bulky and positively charged, which keeps it sitting on the surface rather than sinking into follicles where breakouts form. For these reasons it is generally suitable for acne-prone skin. The ingredient can be paired with heavier oils or waxes in a formula, so anyone tracking breakouts should consider the full ingredient list, not just this antistatic agent.

Summary

Peg-20 Tallow Ammonium Ethosulfate works mainly as an antistatic and lightweight conditioning agent. Its positive charge lets it bind to negatively charged hair fibers, smoothing cuticles and reducing static electricity while its PEG chain keeps the feel light and rinsable. It is a niche but established ingredient in hair care, particularly in conditioners and detangling sprays directed at taming flyaways without heaviness. Current safety data show it is low risk for irritation or acne, though it is not suitable for vegans due to its tallow origin. As with any new product, perform a patch test first to be sure your skin or scalp reacts well.

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