Peg-25 Glyceryl Trioleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-25 Glyceryl Trioleate?

Peg-25 Glyceryl Trioleate is a lab-made ingredient that links natural fatty acids from olive or other vegetable oils with glycerin and then attaches about 25 units of ethylene oxide. The result is a creamy liquid that mixes well with both oil and water. Chemists first explored this type of molecule in the 1970s when brands were searching for gentler alternatives to soap-based emulsifiers. Today it is produced in a two-step process: oleic acid is combined with glycerin to form glyceryl trioleate, then the mixture is reacted with ethylene oxide under controlled heat and pressure. The finished material is purified, tested for safety and supplied as a clear to pale yellow liquid.

You will most often spot Peg-25 Glyceryl Trioleate in rinse-off cleansers, light lotions, makeup removers, hair conditioners, sheet mask essences and some anti-aging creams where a smooth non-greasy feel is desired.

Peg-25 Glyceryl Trioleate’s Cosmetic Benefits/Uses

This ingredient plays one key role that makes many modern formulas possible.

As an emulsifying agent it keeps oil and water blended into a stable, uniform texture. This prevents products from separating on the shelf, improves spreadability during use and helps active ingredients disperse evenly across the skin or hair. The end result is a smoother application, better performance and a pleasant lightweight feel.

Who Can Use Peg-25 Glyceryl Trioleate

This emulsifier is considered suitable for nearly all skin types including dry, normal, combination and oily because it has a light, non occlusive texture that will not leave a heavy film. Most sensitive skin users also tolerate it well, though anyone with a known sensitivity to polyethylene glycols should proceed with caution.

Peg-25 Glyceryl Trioleate is typically sourced from plant oils such as olive or soybean and involves no animal-derived materials, so it is usually acceptable for vegans and vegetarians. If a brand chooses a different feedstock it should be clearly stated on the label.

The ingredient is classed as low risk for women who are pregnant or breastfeeding. It does not penetrate deeply into the skin and has no known hormonal activity, yet this is not medical advice and expectant or nursing mothers should confirm any product choice with their healthcare provider.

It does not cause photosensitivity and will not make skin more prone to sunburn. The ingredient is also fragrance free and carries no nut or gluten allergens, which can be important for some users.

Potential Side Effects/Adverse Reactions

Individual responses to topical Peg-25 Glyceryl Trioleate can vary. The points below list potential reactions, but most people will not experience them when the ingredient is properly formulated and used as directed.

  • Mild transient stinging or burning on very sensitive or compromised skin
  • Temporary redness or itching linked to irritation from polyethylene glycols
  • Rare allergic contact dermatitis in persons already sensitized to PEG compounds
  • Watery eyes or slight eye irritation if the product accidentally gets into the eyes

If any of these effects occur discontinue use and consult a qualified healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5

Peg-25 Glyceryl Trioleate contains oleic acid groups that could in theory clog pores, yet the large PEG portion keeps the molecule water dispersible, reduces its affinity for skin lipids and helps it rinse away. Most formulations use it at low levels purely to stabilize emulsions, so any pore blocking potential is minimal.

Suitable for acne prone or breakout prone skin in most rinse off and lightweight leave on products.

Formulation matters: when paired with heavy oils or waxes the overall product could still feel greasy even if this single ingredient is not highly comedogenic.

Summary

Peg-25 Glyceryl Trioleate is an emulsifier that lets oil and water coexist in a smooth, stable blend. Its PEG chains love water while its fatty acid tails love oil, allowing it to sit at the boundary of both phases and lock them together. This dual nature also gives finished products a light non greasy glide.

The ingredient is moderately popular, turning up more often in cleansers, micellar waters and conditioners than in trend driven serums where brands favor exotic actives.

Safety data place it in the low risk category for irritation, allergy and comedogenicity. Still, skin is unique so performing a quick patch test with any new product containing Peg-25 Glyceryl Trioleate is a sensible habit.

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