Peg-32 Oleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-32 Oleate?

PEG-32 Oleate is a synthetic ingredient created by reacting oleic acid, a fatty acid most commonly obtained from vegetable oils like olive or sunflower, with polyethylene glycol that contains an average of 32 repeating units. The result is a clear or slightly hazy liquid that mixes well with both water and oil.

The cosmetic industry began exploring PEG derivatives in the 1960s as a way to replace animal derived soaps and to make gentle cleansers that worked in hard water. PEG-32 Oleate gained popularity because it could dissolve oily dirt yet feel mild on skin. Over the decades formulators kept it in their toolkits for modern face washes, body washes and makeup removers.

Manufacturing starts with plant based oleic acid that is purified then combined with ethylene oxide in a controlled reaction. The number 32 tells chemists how many ethylene oxide units are attached on average. Careful washing and vacuum stripping remove leftover reactants resulting in a finished raw material that meets cosmetic safety standards.

You will most often see PEG-32 Oleate in liquid cleansers, micellar waters, exfoliating scrubs, shampoos, shower gels, baby washes and occasionally in lightweight lotions or serums where it helps keep oil and water blended.

Peg-32 Oleate’s Cosmetic Benefits/Uses

Formulators reach for PEG-32 Oleate because it performs more than one helpful job at once.

  • Cleansing: Its amphiphilic structure grabs onto oils, makeup and everyday grime so they can be rinsed away with water leaving skin or hair feeling fresh without a tight after-feel.
  • Emulsifying: It helps mix oil and water phases into a stable, uniform product. This prevents separation in bottles and ensures each pump or scoop delivers the same texture and active ingredients.

Who Can Use Peg-32 Oleate

PEG-32 Oleate is generally well tolerated by most skin types including normal, oily, combination and dry because it cleanses without leaving a heavy residue. Sensitive skin usually handles it fine too since it is considered mild, though people with a known sensitivity to polyethylene glycols or fatty acid derivatives may prefer to avoid it.

The ingredient is manufactured from plant derived oleic acid and petroleum sourced ethylene oxide rather than animal materials, so products that rely on it are ordinarily suitable for vegetarians and vegans. If a formula also contains other animal sourced additives that would be stated separately on the label.

Current data show no specific risks linked to topical PEG-32 Oleate during pregnancy or while breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should review any new skincare or personal care item with a qualified health professional first to be safe.

PEG-32 Oleate does not make skin more sensitive to sunlight and has no known effect on tanning or photosensitivity. It also rinses cleanly which lowers the chance of product build-up on scalp or skin.

Potential Side Effects/Adverse Reactions

Side effects from topical PEG-32 Oleate vary from person to person. The following list covers potential reactions yet most users will not experience these issues when the ingredient is formulated correctly and used as directed.

  • Mild skin irritation such as redness stinging or itching especially on compromised or very sensitive skin
  • Contact dermatitis in individuals allergic to polyethylene glycol derivatives or oleic acid based compounds
  • Eye irritation if the cleanser or shampoo accidentally gets into the eyes
  • Dryness or a squeaky feel on over-cleansed skin when products containing high levels of PEG-32 Oleate are used too frequently
  • Rare contamination concerns if manufacturing has not adequately removed trace 1,4-dioxane or ethylene oxide though reputable brands test for this

If you notice any discomfort rash or persistent irritation after using a product with PEG-32 Oleate stop using it and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5

PEG-32 Oleate is highly water soluble and rinses away without leaving a waxy or occlusive film that could clog pores. Its molecular structure keeps it lightweight and easily removable so it rarely traps dead skin cells or sebum. For these reasons it earns a low comedogenic score of 1.

That means most people prone to acne or breakouts can use products containing PEG-32 Oleate without much worry, especially when the ingredient appears in rinse-off formulas like cleansers or shampoos.

Since finished products vary in overall composition a formula heavy in rich oils plus PEG-32 Oleate could still feel greasy on very oily skin, though the ingredient itself is not the culprit.

Summary

PEG-32 Oleate works mainly as a cleanser and emulsifier. Its water-loving polyethylene glycol backbone binds to water while the oleate tail grabs onto oils letting it lift makeup, sunscreen and dirt then wash them away. The same dual nature keeps oil and water from separating which gives lotions, washes and micellar waters a smooth uniform texture.

While not the flashiest name on an ingredient list PEG-32 Oleate remains a quiet staple in many modern formulas thanks to its reliable performance and mild skin feel. It shows up most often in face washes, body cleansers and baby products rather than in trendy leave-on serums.

Safety data and decades of use point to a low risk of irritation or pore clogging for the average person. Still everyone’s skin is different so it is wise to patch test any new product that contains PEG-32 Oleate or other unfamiliar ingredients before full use.

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