Peg-4 Trimethylolpropane Triacrylate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-4 Trimethylolpropane Triacrylate?

PEG-4 Trimethylolpropane Triacrylate is a synthetic ingredient created by reacting trimethylolpropane, acrylic acid and roughly four units of ethylene oxide. The result is a triester that behaves like a light, flexible resin once it sets. Manufacturers first explored this material in industrial coatings, then recognized its film-forming talent made it useful in personal care where a clear, even layer on skin or nails is valuable. Production involves controlled esterification and ethoxylation steps, followed by purification to remove unreacted acids and alcohols. In cosmetics it shows up in peel-off masks, long-wear nail lacquers, liquid lipsticks, brow gels, transfer-resistant foundations and certain hair styling products that need a durable yet breathable finish.

Peg-4 Trimethylolpropane Triacrylate’s Cosmetic Benefits/Uses

This ingredient contributes one primary benefit to beauty formulas.

As a film former it spreads into a thin uniform layer that dries quickly, locking pigments or active ingredients in place and helping products resist smudging, flaking or washing off during the day. The flexible film also adds gloss, improves texture during application and can create a gentle tightening sensation that makes skin look smoother until the product is removed.

Who Can Use Peg-4 Trimethylolpropane Triacrylate

Because it is largely inert once it sets, PEG-4 Trimethylolpropane Triacrylate tends to suit oily, dry, combination and normal skin. Those with very sensitive or compromised skin should proceed carefully since acrylate films can sometimes aggravate pre-existing irritation.

The ingredient is produced entirely through synthetic chemistry and contains no raw materials from animals, so it is considered suitable for both vegans and vegetarians.

Current safety data does not flag any specific risks for women who are pregnant or breastfeeding when the ingredient is used in cosmetics applied as directed. This is not medical advice and anyone who is expecting or nursing should still clear new products with a doctor to be safe.

PEG-4 Trimethylolpropane Triacrylate is not known to cause photosensitivity, and it remains stable under sunlight in finished formulations. The film it forms can slightly tighten the surface which some people might find uncomfortable if they prefer very breathable products.

Potential Side Effects/Adverse Reactions

Responses to topical PEG-4 Trimethylolpropane Triacrylate differ from person to person. The following are potential side effects that could occur even though most users will not experience them when the ingredient has been properly formulated and applied.

  • Contact dermatitis presenting as redness, itching or a rash
  • Allergic sensitization to acrylate compounds after repeated exposure
  • Transient stinging or burning on application to broken or highly reactive skin
  • Eye irritation if the raw ingredient or wet product accidentally enters the eyes
  • Nail brittleness or peeling when used in high concentrations in long-wear polishes

If any of these reactions develop stop using the product immediately and consult a healthcare professional.

Comedogenic Rating

Rating: 0

PEG-4 Trimethylolpropane Triacrylate is a large, cross-linking molecule that sits on the surface rather than seeping into pores. It contains no heavy oils or waxes and does not trap skin sebum, so the likelihood of it blocking follicles is extremely low. For that reason it earns a non-comedogenic score of 0. People who are prone to acne or breakouts can generally use products containing this ingredient without extra concern.

One added point worth noting is that the films it forms rinse away with standard cleansers, so there is little chance of buildup over time that could indirectly contribute to congestion.

Summary

PEG-4 Trimethylolpropane Triacrylate is used in cosmetics mainly as a film former. Once applied it spreads into a thin, clear layer that locks pigments or actives in place, boosts wear time, adds gloss and gives a light tightening feel. Its popularity is modest: formulators appreciate its durability in nail lacquers, long-wear makeup and some styling products, but it is not as common as silicones or traditional acrylates.

Safety reviews show the ingredient to be low risk for most users when used as directed, though sensitive skin can occasionally react. As with any new product it is wise to do a quick patch test before full use just to be safe.

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