Peg-40 Glyceryl Stearate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-40 Glyceryl Stearate?

Peg-40 Glyceryl Stearate is a plant or vegetable derived ingredient that combines stearic acid, a fatty acid usually taken from coconut or palm oil, with glycerin and a chain of polyethylene glycol units. The “40” in its name shows that about forty units of ethylene oxide are added to the base molecule, giving it water-loving and oil-loving parts in a single structure.

Chemists first explored this type of blend in the mid-20th century while searching for gentler alternatives to soap. Its balanced structure let it mix oily and watery ingredients without the harshness of traditional detergents, so it quickly found a place in skin care and hair care labs. Once large-scale ethoxylation equipment became common, the ingredient moved from the lab bench into commercial creams and cleansers.

Manufacture starts with natural stearic acid and glycerin, which are reacted to form glyceryl stearate. Ethylene oxide gas is then carefully added under heat and pressure. By controlling temperature, pressure and reaction time, producers can attach roughly forty ethylene oxide units per molecule. The finished material is purified, tested for purity and supplied as a soft, wax-like solid or thick liquid.

You will spot Peg-40 Glyceryl Stearate in a wide range of products such as facial cleansers, micellar waters, body lotions, sunscreens, makeup removers, hair masks, leave-in conditioners and tinted moisturizers. Its mix-friendly nature lets brands create silky textures that rinse easily and feel light on skin and hair.

Peg-40 Glyceryl Stearate’s Cosmetic Benefits/Uses

This ingredient is valued for two main jobs in personal care formulas.

  • Cleansing: The molecule’s water-loving and oil-loving ends surround dirt, makeup and excess sebum, lifting them away from skin or hair so they rinse off without stripping natural moisture.
  • Emulsifying: It helps water and oil stay blended, stabilizing creams and lotions so they keep a smooth, even texture throughout their shelf life and during use.

Who Can Use Peg-40 Glyceryl Stearate

Products containing Peg-40 Glyceryl Stearate suit most skin types. Dry and normal complexions appreciate its light conditioning feel while combination and oily skin can use it because it does not leave a heavy film. Even sensitive skin generally tolerates it since it is considered mild, though anyone with a history of reactions to polyethylene glycol derivatives should be cautious.

The ingredient is typically sourced from coconut or palm based stearic acid so it is suitable for vegans and vegetarians when the supplier confirms a plant origin. A quick look at the brand’s ingredient sourcing policy can clear up any concerns.

No research shows Peg-40 Glyceryl Stearate poses a risk to women who are pregnant or breastfeeding. Systemic absorption through intact skin is extremely low. Still, this is not medical advice and anyone expecting or nursing should run new skincare products past a qualified doctor to be safe.

The ingredient does not make skin more sensitive to sunlight and can be worn under SPF or makeup without increasing the chance of sunburn. It also works across a broad pH range so it pairs well with acids, retinoids and other actives without stability issues.

Potential Side Effects/Adverse Reactions

Responses to topical Peg-40 Glyceryl Stearate differ from person to person. The effects listed below are only potential outcomes and are unlikely for most users when the ingredient is used at standard cosmetic levels.

  • Mild skin irritation or redness on very reactive skin
  • Contact dermatitis in individuals allergic to polyethylene glycol compounds
  • Eye stinging or watering if the formula accidentally enters the eyes
  • Rare irritation from trace 1,4 dioxane if the raw material was not properly purified

If you develop persistent redness, itching or discomfort discontinue use and consult a healthcare professional.

Comedogenic Rating

Rating: 1/5

Peg-40 Glyceryl Stearate contains a fatty acid tail but the long chain of polyethylene glycol makes the molecule highly water dispersible so it does not sit in pores as readily as pure stearic acid or glyceryl stearate. Most formulation levels are low, further reducing any clogging potential. For these reasons it earns a low score of 1 and is generally suitable for acne-prone or breakout-prone skin.

Formulas that pair it with heavy oils or waxes can still feel occlusive, so the finished product matters more than the single ingredient.

Summary

Peg-40 Glyceryl Stearate works as a cleanser and emulsifier. Its split personality of oil-loving stearic acid and water-loving polyethylene glycol lets it grab onto grime then rinse away clean while holding water and oil together in stable lotions and creams.

The ingredient is a quiet workhorse found in everything from facial washes and micellar waters to sunscreens and hair masks. It is not a trendy headline act but formulators rely on it because it is versatile, mild and easy to incorporate.

Safety reviews show low irritation rates, minimal absorption and no evidence of long-term health risks at cosmetic levels. Still, every skin is unique so it is wise to patch test any new product that contains Peg-40 Glyceryl Stearate before using it all over.

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