Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer?

Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer is a hybrid ingredient made by linking PEG-40 hydrogenated castor oil with isophorone diisocyanate. The process starts with natural castor oil that is fully hydrogenated to make it solid and stable, then ethoxylated to attach about forty units of polyethylene glycol. This PEG-40 hydrogenated castor oil is reacted with IPDI under controlled heat and catalysts to form a flexible urethane copolymer that combines oil-loving and water-loving segments, followed by purification and filtration.

Castor oil has long been valued in soaps and ointments, while urethane chemistry took off in the mid-20th century for coatings and flexible foams. Blending the two ideas gave formulators a way to create clear, smooth films on skin without a heavy, greasy feel. Since the early 2000s this copolymer has appeared in a wide range of personal care goods.

You will most often spot it in moisturizers, leave-on masks, primers, anti-aging serums, liquid foundations, sunscreens, styling creams, hair conditioners and even cleansing balms. Its balance of moisturization, texture enhancement and film-forming ability makes it popular in both skin and hair care.

Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer’s Cosmetic Benefits/Uses

In formulas this ingredient earns its keep by performing several useful roles:

  • Film forming – lays down a thin flexible layer that helps lock in moisture, boosts product longevity and improves resistance to sweat or water
  • Skin conditioning – leaves skin feeling softer and smoother while adding a subtle emollient touch without heaviness
  • Skin protecting – provides a light barrier that shields skin from environmental stress and helps reduce transepidermal water loss
  • Slip modifier – gives creams and serums a pleasant glide so they spread evenly and feel silky rather than tacky
  • Surface modifier – refines the overall texture of a formula, stabilises emulsions and enhances visual clarity for a polished finish

Who Can Use Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer

This multipurpose copolymer suits most skin types. Dry and mature skin benefit from its light occlusive film that prevents moisture loss, while normal and combination skin enjoy the silky finish without greasy residue. Oily or acne-prone users usually tolerate it well because the molecular weight keeps it from sinking deeply into pores, though those who react easily to any PEG derivative may prefer to proceed with caution.

The ingredient comes from plant-derived castor oil combined with fully synthetic components, so it contains no animal matter and is generally considered suitable for both vegetarians and vegans.

No published research shows specific risks for pregnant or breastfeeding women when this copolymer is used topically at normal cosmetic levels. That said this is not medical advice and anyone who is expecting or nursing should show the full ingredient list of any product to their healthcare provider before use.

Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer does not absorb UV light or make skin more sensitive to the sun. It can actually improve the wear time of sunscreens by forming a stable film on the surface.

Potential Side Effects/Adverse Reactions

Reactions to topical Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer vary from person to person. The points below outline potential side effects that are possible yet uncommon when the ingredient is formulated and used correctly. Most people will not notice any of these issues.

  • Mild skin irritation such as redness itching or a transient stinging sensation
  • Allergic contact dermatitis in individuals sensitive to residual isocyanates or PEG compounds
  • Eye irritation if the product migrates into the ocular area
  • Temporary pore congestion on highly clog-prone skin when used in heavy leave-on formulas

If any unwanted reaction occurs stop using the product and seek advice from a qualified healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1/5. Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer is a large, highly branched molecule that mostly remains on the skin surface rather than slipping into pores. While raw castor oil has a mild tendency to clog pores, the hydrogenation, ethoxylation and copolymerisation steps raise the molecular weight and reduce the oily residue, lowering the clogging potential.

Most acne-prone users can use products containing this ingredient without seeing extra breakouts, especially when the formula is lightweight and well balanced.

Keep in mind that very rich leave-on products or layering multiple occlusive ingredients may still overwhelm exceptionally reactive skin.

Summary

Peg-40 Hydrogenated Castor Oil/Ipdi Copolymer works as a film former, skin conditioner, skin protectant, slip enhancer and surface modifier. Its dual water-loving and oil-loving segments let it form a whisper-thin flexible layer that locks in moisture, smooths texture and helps products glide evenly while boosting wear time.

It is not the most famous ingredient on shelves, yet it quietly powers a wide range of moisturisers, primers, sunscreens and hair creams because formulators appreciate its versatility and stability.

Current data and decades of topical use show it to be low risk for irritation or pore blockage at normal cosmetic levels. As with any new skincare ingredient, a small patch test is a smart step before incorporating a full-size product into your routine.

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