Peg-40 Sorbitan Oleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-40 Sorbitan Oleate?

Peg-40 sorbitan oleate is a plant-derived surfactant and emulsifier made by combining sorbitol, a sugar alcohol usually sourced from corn or fruits, with oleic acid obtained from vegetable oils such as olive or sunflower. First the sorbitol is heated to form sorbitan, then it is esterified with oleic acid to create sorbitan oleate. Finally around 40 units of ethylene oxide are added, giving the ingredient its PEG-40 label and water-loving character. Nonionic surfactants like this entered cosmetic labs in the 1940s as gentler alternatives to soap-based cleansers and have stayed popular thanks to their skin-friendly profile.

Because it can keep oil and water blended while also lifting away dirt, Peg-40 sorbitan oleate appears in a wide range of products. You will often spot it in facial cleansers, micellar waters, makeup removers, bath gels, body lotions, sunscreens, lightweight moisturizers, hair conditioners and sheet masks. Its ability to stabilize formulas lets brands create smooth textures that feel pleasant and rinse off without residue.

Peg-40 Sorbitan Oleate’s Cosmetic Benefits/Uses

This multitasker supports both the performance and the feel of many beauty products.

  • Cleansing: Acts as a gentle surfactant that loosens oil, makeup and daily grime so they can be rinsed away with water, leaving skin or hair fresh without a tight sensation
  • Emulsifying: Keeps oil-based and water-based ingredients blended, preventing separation in the bottle and ensuring each application delivers the same smooth consistent formula

Who Can Use Peg-40 Sorbitan Oleate

This ingredient is generally well tolerated by all skin types including oily, dry, combination and sensitive skin because it is a mild nonionic surfactant that cleanses without stripping. People with very reactive or eczema-prone skin should still monitor for irritation when using any new cleanser since surfactants can sometimes disrupt a fragile barrier.

Peg-40 sorbitan oleate is typically produced from plant sources so products using it are usually suitable for vegetarians and vegans. Anyone following a strict lifestyle may wish to confirm that the specific formula also meets cruelty-free standards and that no animal-derived processing aids were used.

The ingredient has a long track record of use in personal care and is considered low risk for women who are pregnant or breastfeeding. This is not medical advice and expectant or nursing mothers should show the full ingredient list of any product to their healthcare provider just to be safe.

Peg-40 sorbitan oleate does not make skin more sensitive to sunlight and can be worn day or night without special sun precautions beyond the normal recommendation to apply sunscreen daily.

Potential Side Effects/Adverse Reactions

Reactions to topical Peg-40 sorbitan oleate vary from person to person. The points below outline potential side effects that have been reported in rare cases. When the ingredient is used correctly in a well-formulated product most people will not experience these issues.

  • Mild redness or stinging in very sensitive or compromised skin
  • Transient eye irritation if the product accidentally gets into the eyes
  • Dry or tight feeling after cleansing when formulas contain a high overall surfactant load
  • Allergic contact dermatitis in individuals allergic to sorbitan esters or ethoxylated ingredients
  • Trace 1,4-dioxane residues if the manufacturer has not properly purified the PEG portion

If you notice any persistent discomfort or visible irritation stop using the product and consult a qualified healthcare professional.

Comedogenic Rating

Rating: 1 out of 5. Peg-40 sorbitan oleate is primarily water soluble thanks to its long PEG chain so it does not linger in pores the way heavier oils can. It is also used at low concentrations that rinse or wipe away easily which further reduces the chance of clogging. Formulas that include lots of richer plant butters or waxes may still feel heavier but that would be due to those other ingredients, not the Peg-40 sorbitan oleate itself.

Suitable for acne-prone skin in most cases.

As with any surfactant the overall recipe matters; pairing it with calming humectants and lightweight emollients will keep breakouts at bay while harsh adjuncts could tip a formula toward irritation that secondarily triggers pimples.

Summary

Peg-40 sorbitan oleate works as a mild cleanser and a reliable emulsifier. Its oleate portion anchors to oils while the 40-unit PEG chain grabs water allowing it to bridge both phases and either keep them blended or lift grime into the rinse water. This dual nature lets brands create clear micellar waters silky lotions and non stripping face washes.

The ingredient has stayed popular since the mid 20th century because it is plant derived easy to work with cost effective and gentle enough for daily use. You will see it on labels from budget body wash to high end serum cleansers.

Regulatory reviews and decades of consumer use show it is low risk for most people when properly purified. Even so skin can be unpredictable so it is always smart to try a small patch when starting any new product that contains Peg-40 sorbitan oleate just to be safe.

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