Peg-5 Glyceryl Trioleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-5 Glyceryl Trioleate?

Peg-5 Glyceryl Trioleate is a plant derived lipid that links glycerin from vegetable oils with three molecules of oleic acid then attaches an average of five ethylene oxide units. The result is a water loving yet oily ester that can bridge the gap between oil and water. First explored in the late 1970s as formulators searched for gentler alternatives to petrolatum based emulsifiers, it quickly gained traction in skin care and hair care labs for its silky feel and reliable stability.

Manufacturing starts with food grade glycerin and sustainably sourced oleic acid usually from sunflower or olive oil. These are esterified to create glyceryl trioleate. The trioleate is then reacted with controlled amounts of ethylene oxide, a process called ethoxylation, to yield the pegylated final material. The average of five ethylene oxide units keeps the ingredient mild while giving it the right balance to mix with both water and oil phases.

You will most often see Peg-5 Glyceryl Trioleate in moisturizers, cleansing balms and oils, lightweight lotions, leave-on hair conditioners, baby wipes, makeup removers and pampering masks where a soft cushiony after-feel is desired.

Peg-5 Glyceryl Trioleate’s Cosmetic Benefits/Uses

This versatile molecule supports both the texture and the skin feel of many formulas

  • Emollient: Spreads smoothly across skin or hair filling in microscopic gaps on the surface so it feels softer and more supple
  • Emulsifying: Helps oil and water stay mixed which gives creams and lotions a uniform appearance, prevents separation during storage and ensures even delivery of active ingredients with each use

Who Can Use Peg-5 Glyceryl Trioleate

Peg-5 Glyceryl Trioleate is gentle enough for most skin types. Normal and dry skin benefit from its silky cushioning feel while combination and sensitive skin usually tolerate it because it is lightweight and free of common irritants. Very oily or acne-prone complexions can also use it since the molecule is not highly occlusive though extremely breakout-prone users may prefer to monitor how their skin responds.

The ingredient is made from plant sources and contains no animal by-products so it fits vegan and vegetarian lifestyles.

Current safety data show no issues for women who are pregnant or breastfeeding when the ingredient appears at typical cosmetic levels. This information is educational only; anyone who is expecting or nursing should run their skin care choices by a doctor to be safe.

Peg-5 Glyceryl Trioleate does not cause photosensitivity so it will not make skin more likely to burn in the sun. It is also fragrance free and gluten free which may matter to some users.

Potential Side Effects/Adverse Reactions

Responses to topical Peg-5 Glyceryl Trioleate vary from person to person. The points below list potential side effects that could occur but most users will not experience them when the ingredient is properly formulated into a finished product.

  • Transient redness or mild stinging on very sensitive skin
  • Rare allergic contact dermatitis in individuals reactive to polyethylene glycol derivatives
  • Slight clogging of pores in people extremely prone to comedones
  • Irritation if applied to broken or already inflamed skin
  • Trace contamination concerns with poorly purified raw material such as residual ethylene oxide or 1,4-dioxane though regulatory limits make this unlikely in retail products

If any discomfort or visible reaction occurs stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 2 / 5

Peg-5 Glyceryl Trioleate contains fatty acid chains that can potentially sit in pores yet its pegylated structure keeps the molecule fairly water compatible which lowers the chance of buildup. Most users will find it lighter than straight plant oils but still richer than fully water soluble ingredients.

Generally suitable for acne-prone skin though those who clog very easily may prefer to watch how their skin responds after repeated use.

No published studies link this ingredient to persistent breakouts and it rarely appears in the high-oil concentrations that trigger congestion, which helps keep its real-world clogging risk modest.

Summary

Peg-5 Glyceryl Trioleate works as an emollient that smooths rough texture and an emulsifier that keeps water and oil perfectly blended. Its trioleate backbone provides a cushiony slip while the five ethylene oxide units give it just enough water affinity to stabilize creams, cleansing balms and conditioners without feeling greasy.

The ingredient enjoys steady but not blockbuster popularity in skincare and haircare formulas aimed at a soft velvety finish. Formulators appreciate its balance of performance and mildness even if it does not enjoy the marketing spotlight of buzzier actives.

Current safety reviews rate it as low risk with minimal irritation or sensitization reports. As with any new cosmetic product it is smart to patch test first so you can be sure your individual skin tolerates the formula comfortably.

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