Peg-5M: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-5M?

Peg-5M is a synthetic polymer from the family of polyethylene glycols, created by linking together about five thousand units of ethylene oxide. Chemists describe it as poly(oxy-1,2-ethanediyl) alpha-hydro omega-hydroxy with a 5000 mol ethylene oxide average, but in everyday terms it is a long water-loving chain that dissolves easily in liquids. Peg-type ingredients have been around since the mid-1900s when scientists looked for safer substitutes for natural gums and waxes that could be inconsistent or spoil. Production starts with ethylene oxide, a small gas molecule, that undergoes controlled polymerization until the chain reaches the desired length. The process yields a smooth white solid or thick paste that blends readily with water or alcohol.

Because it is stable, non-greasy and adaptable, Peg-5M shows up in many personal care items. You will most often see it in face masks, moisturizers, serums, anti-aging creams, shampoos, hair conditioners, styling gels, shaving foams and even toothpaste where it improves texture and spreadability.

Peg-5M’s Cosmetic Benefits/Uses

Peg-5M brings several formulating perks that help products look and feel better on the skin or hair.

  • Binding: Keeps solid particles like pigments or exfoliating beads evenly suspended so they do not sink or clump, giving a uniform application every time
  • Emulsion stabilising: Strengthens the mix of oil and water, stopping them from separating during storage or use which means a longer shelf life and consistent performance
  • Viscosity controlling: Thickens watery formulas or thins heavy ones to reach the ideal texture making creams silky, gels smooth and lotions easy to spread

Who Can Use Peg-5M

Peg-5M is generally well tolerated by all skin types including dry, oily, combination and sensitive skin because it is non greasy, water soluble and has a low chance of clogging pores. Those with very reactive or allergy-prone skin may still want to monitor for individual irritation since every complexion is unique.

The ingredient is synthetic and produced without animal by-products so it is considered suitable for vegans and vegetarians.

No data suggest Peg-5M poses a specific risk to women who are pregnant or breastfeeding when used topically. This is not medical advice and anyone who is expecting or nursing should check with a healthcare professional before adding new skincare just to be safe.

Peg-5M does not absorb UV light or make skin more sensitive to the sun so it is not known to cause photosensitivity. It is also odorless and colorless which can be useful for people who wish to avoid added fragrances or dyes.

Potential Side Effects/Adverse Reactions

Reactions to topical Peg-5M can differ from person to person. The effects listed below are possible yet unlikely when the ingredient is used correctly in a finished cosmetic product.

  • Mild redness or stinging in very sensitive skin
  • Temporary dryness if used in high amounts without other moisturizers
  • Rare contact dermatitis in individuals with a specific polyethylene glycol allergy

If any irritation or discomfort develops stop using the product and consult a healthcare professional if symptoms persist.

Comedogenic Rating

Rating: 0 out of 5

Peg-5M is highly water soluble, leaves virtually no oily residue and has a very large molecular size that sits on the surface instead of seeping into pores. Because of these traits it does not contribute to the buildup of sebum or dead cells that can plug follicles. For this reason it is considered non-comedogenic.

People who are prone to acne or frequent breakouts can generally use products containing Peg-5M without added concern.

The only caveat is that finished formulas matter: if Peg-5M appears alongside heavy oils or waxes, those other ingredients could still trigger clogged pores even though Peg-5M itself does not.

Summary

Peg-5M is a synthetic polyethylene glycol that shines at binding particles, stabilising oil-water mixes and fine-tuning thickness. Its long, water-loving chains wrap around solid bits to keep them suspended, form a flexible film that keeps oils and water blended and trap water molecules to boost or reduce viscosity as needed.

While not a headline ingredient, it is a quiet workhorse found in a wide range of skincare, haircare and oral care products because formulators appreciate its reliability and ease of use.

Safety profiles rate it as low risk for irritation, non-comedogenic and suitable for almost all skin types. As with any new cosmetic a quick patch test is wise to make sure your skin agrees with the full formula.

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