Peg-60 Polyglyceryl-4 Hexaacrylate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-60 Polyglyceryl-4 Hexaacrylate?

Peg-60 Polyglyceryl-4 Hexaacrylate is a synthetic ingredient created by attaching roughly 60 units of polyethylene glycol to a polyglyceryl backbone that has been modified with hexaacrylate groups. The result is a large water-loving molecule that can spread smoothly over skin and hair while forming a flexible film. It is derived from glycerin and acrylic acid derivatives that go through controlled esterification and polymerization steps, then are purified to cosmetic grade. The compound first appeared in professional hair styling products in the late 1990s when chemists were looking for gentler film formers to replace harsher styling resins. Today it is produced in modern facilities that meet Good Manufacturing Practice standards, ensuring consistent purity and performance.

You will most often see Peg-60 Polyglyceryl-4 Hexaacrylate in rinse-off and leave-on products that benefit from a lightweight yet durable coating. These include sheet masks, wash-off clay masks, setting sprays, curl-defining creams, anti-frizz serums, tinted moisturizers and long-wear foundations where a soft flexible film helps pigments stay put.

Peg-60 Polyglyceryl-4 Hexaacrylate’s Cosmetic Benefits/Uses

This ingredient is prized for its ability to improve product performance through film formation.

  • Film forming: Once applied it creates a breathable micro-thin layer that locks moisture in, smooths the skin surface, enhances spreadability and helps active ingredients or colorants adhere better. In hair care it supplies soft hold, reduces flyaways and adds a subtle gloss without stiffness.

Who Can Use Peg-60 Polyglyceryl-4 Hexaacrylate

Because the molecule is water soluble and non-oily it suits most skin types, including oily, combination, normal and dry skin. Sensitive skin generally tolerates it well since it is free of common irritants like fragrance and essential oils. Those with very reactive or eczema-prone skin may still wish to choose formulas with low overall additive loads, since a long ingredient list can compound sensitivity.

The compound is synthesised from plant-derived glycerin and petroleum-free acrylic monomers, so it is suitable for vegans and vegetarians. No animal by-products or animal testing are required in its manufacture by reputable suppliers.

Current safety data shows no specific concerns for pregnancy or breastfeeding when the ingredient is used topically at the levels found in cosmetic products. This is not medical advice and anyone who is pregnant or nursing should confirm product choices with a healthcare professional just to be safe.

Peg-60 Polyglyceryl-4 Hexaacrylate does not increase photosensitivity, so it will not make skin more prone to sunburn. Normal daily sunscreen habits are still recommended.

Potential Side Effects/Adverse Reactions

Responses to topical Peg-60 Polyglyceryl-4 Hexaacrylate vary from person to person. The effects listed below are possible but unlikely for most users when the ingredient is formulated and used correctly.

  • Mild skin irritation
  • Transient redness or warmth at the application site
  • Stinging on compromised or freshly exfoliated skin
  • Allergic contact dermatitis in individuals sensitised to polyacrylates

If any discomfort or persistent reaction occurs discontinue use and consult a healthcare professional.

Comedogenic Rating

Rating: 0 / 5

Peg-60 Polyglyceryl-4 Hexaacrylate is a large water loving molecule that stays mostly on the skin surface and dissolves easily when rinsed. Because it contains no fatty acids or heavy oils it is unlikely to block pores or trap sebum. Its main job is to lay down a micro-thin breathable film that washes off without residue, so it earns the lowest possible comedogenic score. This makes it a suitable choice for people who are prone to acne or breakouts. The only caveat is that a formula rich in other pore-clogging ingredients could still cause problems, but those issues would not stem from this polymer itself.

Summary

Peg-60 Polyglyceryl-4 Hexaacrylate is a water soluble film former that smooths skin, locks light moisture, boosts spreadability and helps color or styling agents stay put. It does this by creating a flexible micro-layer that binds to the surface then rinses away cleanly. While not a mainstream household name, it has a steady presence in modern masks, setting sprays and lightweight hair products where a soft non-sticky finish is valued.

Current safety data classifies it as low risk with minimal irritation potential at typical use levels. Still, skin is personal so patch testing any new product that features this ingredient is a smart precaution.

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