Peg-9 Dimethicone Phosphate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg-9 Dimethicone Phosphate?

Peg-9 Dimethicone Phosphate is a lab-made ingredient created by joining a silicone known as dimethicone with phosphoric acid and nine units of polyethylene glycol. The result is a silky liquid that mixes well with both water and oil, something plain silicones cannot do on their own. First explored in the late 1990s as chemists searched for lighter, more versatile silicones, it soon found a place in hair care where smooth feel and easy rinse-off are prized. Making it starts with standard cosmetic-grade dimethicone. Chemists attach short chains of polyethylene glycol, then react the blend with phosphoric acid under controlled heat. This step adds the phosphate group, which boosts its ability to spread and stay put on hair strands without feeling greasy. You will most often spot Peg-9 Dimethicone Phosphate in leave-in conditioners, rinse-out conditioners, co-wash formulas, styling creams, curl definers, color-protect sprays and damage-repair masks.

Peg-9 Dimethicone Phosphate’s Cosmetic Benefits/Uses

The ingredient appears on labels mainly for its hair conditioning role. It coats the hair shaft in a thin, breathable layer that smooths cuticles, reduces friction and helps detangle. Because it is partly water-loving, it rinses off more easily than heavier silicones so it is less likely to build up over time. The result is softer, shinier, more manageable hair that still feels light and clean.

Who Can Use Peg-9 Dimethicone Phosphate

This ingredient is generally suitable for all skin and scalp types including oily, dry, combination and sensitive since it forms a lightweight breathable film that is unlikely to clog pores or trap heat. People who know they react badly to silicones, PEGs or phosphate esters should proceed with caution because the molecule contains all three components.

Peg-9 Dimethicone Phosphate is synthesized entirely from non-animal sources so it is appropriate for vegans and vegetarians. Most reputable brands also avoid animal testing for the finished product, though consumers who follow a strict cruelty-free lifestyle may still want to confirm the brand’s policy.

Current safety data show no reproductive or developmental red flags, meaning pregnant or breastfeeding women can generally use products containing this ingredient. That said this is not medical advice and anyone who is expecting or nursing should check with a healthcare professional before adding new personal care products to their routine just to be sure.

The molecule does not absorb UV light and is not known to make skin or scalp more sensitive to the sun so it does not cause photosensitivity. It is also compatible with most other common hair care ingredients including proteins, oils and mild acids.

Potential Side Effects/Adverse Reactions

Responses to topical Peg-9 Dimethicone Phosphate differ from person to person. The effects listed below are possible but uncommon when the ingredient is used at standard cosmetic levels in a well-formulated product.

  • Mild scalp or skin irritation
  • Allergic contact dermatitis in individuals sensitive to silicones or PEG derivatives
  • Eye stinging if the product accidentally drips into the eyes
  • Build-up and limp feel on very fine hair when used excessively without proper cleansing

If you experience any unwanted reaction discontinue use and consult a healthcare professional.

Comedogenic Rating

Rating: 1 – Peg-9 Dimethicone Phosphate forms a light, partially water-soluble film that is easily removed with routine cleansing, so it has very little tendency to block pores. Its large molecular size keeps it mostly on the surface of skin and hair, limiting the chance of it sinking into follicles and triggering breakouts. Because of this low rating it is generally considered fine for people who are prone to acne or congestion. Products with heavy oils or waxes alongside it could still pose a clogging risk so check the full ingredient list.

Summary

Peg-9 Dimethicone Phosphate is used in hair care to smooth cuticles, reduce friction and boost shine while rinsing away cleanly thanks to its phosphate and PEG portions. The hybrid structure lets it spread like a silicone yet wash out more like a gentle surfactant, giving soft slip without weighed-down buildup.

It is not the most famous silicone derivative on the market, but formulators appreciate its balance of conditioning power and light feel so you will spot it in a growing number of conditioners, leave-ins and styling creams aimed at fine to medium hair.

Current research and decades of cosmetic use show it to be low risk for irritation, sensitization or toxicity. Still, everyone’s skin and scalp are unique so it is smart to patch test any new product that features this ingredient before full application.

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