Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
Share:
Inside this article:

We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone?

Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone is a silicone based ingredient that blends polyethylene glycol (PEG) and polypropylene glycol (PPG) units with a lightweight caprylyl siloxane chain. The result is a silky fluid that mixes well with both water and oil, helping formulas feel smooth and non greasy. It was first developed in the late 1990s when chemists looked for gentler alternatives to heavy silicones that could still add slip and shine. The ingredient is made by linking the PEG and PPG blocks to a phenylisopropyl caprylyl dimethicone backbone through controlled chemical reactions carried out under heat and vacuum. This process lets makers fine tune the balance between water loving and oil loving parts, giving the material its versatile feel.

You will most often find Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone in lightweight moisturizers, primers, foundations, hair serums, leave in conditioners, anti frizz sprays, sunscreens and sheet masks. Its ability to keep oil and water mixed makes it popular in creamy lotions and spray on mists where a clear stable finish matters.

Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone’s Cosmetic Benefits/Uses

This multi tasking silicone brings several practical benefits to everyday beauty products.

  • Emulsion stabilising: Helps water and oil stay blended so creams do not separate on the shelf or on the skin. This keeps textures silky and spreadable from the first use to the last.
  • Hair conditioning: Coats strands with a thin film that smooths cuticles, cuts down frizz and adds a soft touchable shine without weighing hair down.
  • Skin conditioning: Forms a breathable layer that locks in moisture, gives a velvety after feel and helps makeup glide on more evenly.

Who Can Use Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone

This silicone based conditioner suits most skin types. Its lightweight texture makes it a welcome addition for oily and combination skin while the soft moisture-locking film can help relieve dryness and rough patches. Extremely acne-prone or silicone-sensitive users may prefer to monitor use since any film-forming agent has the potential to trap excess sebum if layers are not cleansed off thoroughly.

The ingredient is produced entirely through synthetic chemistry so it contains no animal-derived components. That means it is generally acceptable for vegans and vegetarians provided the finished product is certified cruelty free by the brand.

No evidence suggests the molecule poses a risk to pregnant or breastfeeding women because it is large, sits mainly on the surface and is used at low levels in rinse-off or leave-on formulas. This is not medical advice so anyone who is expecting or nursing should review all personal care products with a qualified healthcare provider.

Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone does not increase photosensitivity. Standard daily sun protection is still recommended for overall skin health.

Potential Side Effects/Adverse Reactions

Responses to topical Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone can vary by individual. The points below outline potential issues but most people will not notice any problems when the ingredient is used correctly in a well-formulated product.

• Local redness or mild irritation on very sensitive skin

• Allergic contact dermatitis in rare cases of silicone allergy

• Temporary clogged pores or breakouts if heavy layers build up and are not washed away

• Product residue on the scalp or hair shaft that can lead to dullness between washes

• Stinging or watering of the eyes if a facial product migrates into the eye area

If any unwanted reaction occurs stop using the product and seek advice from a dermatologist or healthcare professional.

Comedogenic Rating

Rating: 1 out of 5

Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone is a large silicone-based molecule that mostly stays on the surface instead of sinking into pores. Its PEG and PPG portions give it a light, water-compatible character that helps it rinse away more easily than heavier dimethicones, lowering the chance of pore blockage. For this reason formulators consider it very low on the comedogenic scale.

People who are prone to acne or frequent breakouts can generally use products containing this ingredient without major concern, provided the overall formula suits their skin and is removed properly at the end of the day.

As with any film-former, buildup from multiple layers or pairing it with rich occlusive oils could nudge the risk higher, so balanced cleansing is important to keep skin clear.

Summary

Peg/Ppg-20/20 Phenylisopropyl Caprylyl Dimethicone works as an emulsion stabiliser, hair conditioner and skin conditioner. Its hybrid silicone-PEG-PPG structure lets it sit comfortably between water and oil phases, keeping lotions uniform, adding slip and forming a thin breathable film that smooths both skin and hair.

While it is not as famous as classic dimethicone it shows up in modern lightweight moisturisers, primers and anti-frizz sprays because chemists value its versatility and subtle feel.

Current safety data rates the ingredient as low risk with minimal irritation potential at standard use levels. Still, individual skin can react differently, so doing a small patch test when trying any new product containing this silicone is a smart move for extra peace of mind.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search