Perfluorononyl Dimethicone: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Perfluorononyl Dimethicone?

Perfluorononyl Dimethicone is a specialty silicone that has been chemically bonded to a perfluorinated nine-carbon chain. In plain terms it is a man-made ingredient that mixes the slip and flexibility of classic silicones with the water-repelling power of fluorinated compounds. It starts with dimethicone, a well-known silicone derived from silica. Through a process called hydrosilylation, chemists attach a nonadecafluorononyl propyl group to the silicone backbone, giving the finished material its unique dual nature: part silicone, part fluorocarbon.

Silicones entered skin care in the 1950s thanks to their smooth feel and protective qualities. As makeup and skin care formulas evolved, brands wanted ingredients that could resist water and oil while remaining light on the skin. By the early 2000s fluorinated silicones like Perfluorononyl Dimethicone answered that need, bringing longer wear and a soft touch to many products.

Today you will spot this ingredient in long-wear foundations, primers, BB creams, sunscreens, color cosmetics, moisturizers, sheet masks and hair-smoothing serums. It helps these formulas glide on evenly, stay put through heat and humidity and leave a velvety finish without weight or stickiness.

Perfluorononyl Dimethicone’s Cosmetic Benefits/Uses

Its main job in personal care is classified as skin conditioning, which covers several practical perks for both product and user.

As a skin-conditioning agent Perfluorononyl Dimethicone forms a thin flexible film that smooths the skin surface, fills in fine lines and reduces moisture loss. This film is breathable so it does not feel heavy, yet it resists sweat and sebum, helping makeup last longer. The ingredient also improves spreadability which lets formulas apply more evenly and reduces the amount of product needed.

Who Can Use Perfluorononyl Dimethicone

This ingredient suits most skin types including normal, dry, oily, combination and even sensitive skin because its film is light and non-greasy. Those who struggle with very acne-prone skin or who know they react to silicones might want to watch for clogged pores or a heavy feel, though such issues are uncommon.

Perfluorononyl Dimethicone is made in a lab from mineral sources and contains no animal parts, so it is generally considered suitable for vegans and vegetarians. Always check the full formula to be sure the finished product meets personal cruelty-free standards.

The large size of the molecule means it stays on the surface of the skin and is not expected to enter the bloodstream, so it is viewed as low risk for women who are pregnant or breastfeeding. This is not medical advice and anyone who is expecting or nursing should show any new skincare product to a doctor before use just to be safe.

The ingredient does not make skin more sensitive to sunlight and can even add a slight water-resistant shield when layered over sunscreen, though it has no UV-blocking power on its own.

Potential Side Effects/Adverse Reactions

Responses to topical Perfluorononyl Dimethicone differ from person to person. The points below cover possible but unlikely issues when the ingredient is used in a well-made product.

  • Mild skin irritation such as redness or itching in people who are sensitive to silicones
  • Temporary clogged pores or breakouts in very acne-prone skin due to the film it forms
  • Eye stinging or watering if the product is accidentally rubbed into the eyes
  • Contact dermatitis in rare cases of specific allergy to the compound
  • Build-up on hair shafts leading to a heavy feel if used in leave-in hair products without proper cleansing

If any discomfort, rash or persistent breakout appears stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1/5. Perfluorononyl Dimethicone sits on the surface as a large, inert molecule and does not mix with skin oils, so it is unlikely to block pores for most users. Because it still forms a light film some very oily or highly acne-prone skins may notice occasional congestion, which is why it is not rated a perfect zero. Overall it is considered low risk for breakouts and can be used by people who are prone to acne, though individual reactions can vary. If layered with many heavy occlusives in the same routine the chance of trapped sebum can rise slightly, so keep total product load in mind.

Summary

Perfluorononyl Dimethicone conditions skin by laying down a thin flexible film that smooths texture, cuts moisture loss and boosts the wear of makeup and sunscreen. Its silicone backbone gives slip and softness while the fluorinated tail fends off water and oil, giving formulas a long-lasting comfortable feel. The ingredient is moderately popular in long-wear foundations, primers and hybrid skincare since it adds performance without heaviness yet it remains a niche choice compared with common silicones like dimethicone.

Current safety data show it is stable, non-sensitizing and unlikely to penetrate living skin so routine use is considered safe for healthy adults. As with any new cosmetic ingredient it is smart to patch test a product first to make sure your own skin agrees with it.

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