Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer?

Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer is a man-made ingredient created by combining three building blocks: phthalic anhydride, the simple moisturizer glycerin, and glycidyl decanoate, which comes from decanoic acid found in vegetable oils. When these parts are reacted together they form a long chain, or polymer, that behaves very differently from the raw materials it starts with. The finished material looks like a clear to slightly hazy resin that melts or dissolves into cosmetic bases.

Polyesters like this one first appeared in paints and coatings where they laid down smooth protective films. As cosmetic chemists searched for lightweight ways to improve texture and wear in makeup they borrowed the same technology. Over time safety testing confirmed that the polymer stayed on the skin’s surface rather than soaking in, so it began showing up in personal care products.

The copolymer is produced in a controlled reactor where the three starting ingredients are heated and slowly linked together. Once the reaction reaches the right size of chain, the mixture is cooled, purified, and ground or melted into a form that blends easily with oils or solvents used in cosmetics.

You will most often see Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer in color cosmetics such as foundations, mascaras, eyeliners, lipsticks, and nail treatments. It also appears in sunscreen sticks, long-wear primers, peel-off masks, and some hair styling products that aim to create flexible hold.

Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer’s Cosmetic Benefits/Uses

This multitasking polymer improves both the feel and performance of many formulas.

  • Film forming: Creates a thin breathable layer that locks pigments in place, boosts water and smudge resistance, and helps active ingredients stay on the skin or hair longer
  • Viscosity controlling: Thickens or stabilizes emulsions so creams and gels spread smoothly without dripping, giving products a silky glide and consistent finish

Who Can Use Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer

This polymer works for most skin types including oily, combination, normal and mature skin. Dry and sensitive skin usually tolerate it as well because the ingredient stays on the surface without stripping moisture or adding fragrance. People with very reactive or allergy-prone skin should still check the full ingredient list since the copolymer is often combined with colorants or solvents that could be irritating.

The ingredient is made from synthetic raw materials and vegetable derived decanoic acid so it fits vegan and vegetarian preferences. No animal by-products are used during manufacture.

Current safety data show no specific risks for pregnant or breastfeeding women when the polymer is used in cosmetics. This is not medical advice and anyone who is pregnant or nursing should show any product they plan to use to their healthcare provider to be sure it fits their personal situation.

Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer does not increase sun sensitivity and can even help keep sunscreen actives in place. There are no known interactions with common skincare actives like retinoids, AHAs or vitamin C.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer can vary from person to person. The following are potential reactions though most users will not experience them when the ingredient is properly formulated and used as intended.

  • Mild skin redness or itching in individuals sensitive to polyester resins
  • Eye irritation if the raw material is used at high levels near the lash line
  • Contact dermatitis triggered by residual monomers or solvents left in poor quality batches
  • Buildup on hair shafts that can weigh down very fine hair

If any irritation or discomfort develops stop using the product and consult a medical professional if symptoms persist.

Comedogenic Rating

Rating: 1 / 5

This large polyester molecule sits on top of the skin, creates a breathable film, and is not greasy so it rarely blocks pores. It can trap existing oil or debris if layered too thickly which is why it is not rated a perfect zero, but most formulations include it at levels that remain lightweight.

Overall it is considered suitable for people who are prone to acne or breakouts.

Because it is usually paired with waxes, pigments or silicones, the finished product’s full recipe has a bigger impact on pore clogging than the copolymer itself.

Summary

Phthalic Anhydride/Glycerin/Glycidyl Decanoate Copolymer is mainly used to form an invisible flexible film that holds pigments and actives in place and to fine tune a product’s thickness for a smooth glide. It accomplishes these tasks through its long chain structure which links together on the skin or hair creating a lightweight mesh while its bulky backbone adds body to creams and gels.

While effective it is not as famous as silicones or acrylate polymers, appearing mostly in long wear makeup nail care and certain styling products rather than everyday lotions.

Safety assessments show it is largely inert, stays on the surface, and poses low irritation risk. As with any new cosmetic product it is wise to do a small patch test first to be sure your individual skin agrees with the full formula.

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