Polyacrylate-40: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyacrylate-40?

Polyacrylate-40 is a man-made polymer created by joining together small building blocks called acrylate monomers. Its full chemical name is 2-Propenoic acid, 2-methyl-, 2-methylpropyl ester, polymer with 1-(1,1-dimethylethyl)-4-ethenylbenzene, 1-ethenyl-4-methylbenzene and 2-ethylhexyl 2-propenoate. In everyday terms it is a clear lightweight plastic that can swell in water and form a smooth flexible layer on the skin. The raw materials come from petrochemical sources such as propylene and styrene, which are first purified then reacted under heat, pressure and special catalysts to form long chain molecules. After polymerization the material is dried and milled into a fine white powder that dissolves or disperses easily in water-based or alcohol-based formulas.

Polyacrylate-40 started appearing in personal care in the late 1980s when formulators looked for alternatives to natural gums that could give a lighter feel. Because it can create a thin breathable film it soon became popular in styling gels, sunscreens and long-wear makeup. Today you will also find it in sheet mask essences, anti-aging serums, oil-free moisturizers, peel-off masks and even some liquid lipsticks where it helps pigment stay put.

Polyacrylate-40’s Cosmetic Benefits/Uses

In skin and hair care Polyacrylate-40 serves one main purpose that brings several practical advantages to a formula.

As a film forming agent it spreads over the skin or hair and dries to an invisible flexible layer. This light film helps lock in moisture, improves product wear time, reduces flaking in styling products and keeps active ingredients in close contact with the skin for better performance.

Who Can Use Polyacrylate-40

Polyacrylate-40 is considered safe for most skin types including oily, combination, normal and dry skin because it sits on the surface rather than penetrating deeply. Sensitive or compromised skin can usually tolerate it as well although people with a known sensitivity to acrylic polymers should avoid it as a precaution.

The polymer is synthetically produced from petrochemical sources with no animal derived raw materials or processing aids so it is suitable for both vegans and vegetarians.

No data indicate that topical Polyacrylate-40 poses a risk during pregnancy or while breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should show the full ingredient list of any product to their healthcare provider before using it.

The ingredient does not increase skin photosensitivity so it will not make skin more prone to sunburn. As with any film former it can reduce the breathability of very occlusive formulas which may feel heavy in hot humid climates.

Potential Side Effects/Adverse Reactions

Responses to topical Polyacrylate-40 vary from person to person. The points below list potential reactions yet they remain uncommon when the ingredient is used at the low levels typical in cosmetics.

  • Mild redness or stinging in individuals allergic to acrylic compounds
  • Tight or dry feeling if layered heavily or used in a high hold styling gel
  • Eye irritation if the raw powder or finished product gets into the eyes
  • Rare cases of contact dermatitis after prolonged use on compromised skin

If any of these reactions occur stop using the product and seek advice from a qualified medical professional.

Comedogenic Rating

Polyacrylate-40 scores a 1 out of 5 on the comedogenic scale. The polymer sits on top of the skin and does not supply fatty acids or oils that typically clog pores, but its film can trap existing sebum and debris in very heavy or occlusive formulas, hence the slight bump above zero. Overall it is unlikely to provoke breakouts so it is generally acceptable for acne-prone users. Formulators sometimes pair it with oil-absorbing powders or lightweight humectants to keep the finish breathable and lower any pore-clogging risk.

Summary

Polyacrylate-40 is mainly valued for its film forming ability that locks in moisture, keeps actives in place and boosts the staying power of makeup and hair products. By swelling in water it creates a flexible mesh that dries smooth and clear after application. While it is far from a trendy natural extract it remains a quiet workhorse in gels, serums, sunscreens and long-wear cosmetics because it delivers dependable performance at low cost.

Current safety data show a low irritation and sensitization profile when used at cosmetic levels. Still, everyone’s skin is unique so when you pick up a new product with Polyacrylate-40 it is smart to patch test first to make sure your skin agrees with the formula.

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