Polyacrylic Acid Crosspolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyacrylic Acid Crosspolymer?

Polyacrylic Acid Crosspolymer is a man-made polymer created by linking acrylic acid units with two helper molecules called PPG-8 dimethacrylate and PEG-3 diacrylate. The crossing of these chains turns the material from a simple straight line into a three-dimensional net that swells in water and holds liquids in place. Because it is fully synthetic it does not rely on animal or plant sources, giving formulators a steady supply with consistent quality.

Researchers first explored acrylic acid polymers for medical dressings in the 1960s. Cosmetic chemists soon noticed that these polymers could stop creams from separating and give gels their smooth bounce. By the early 1990s crosslinked grades like Polyacrylic Acid Crosspolymer were common in moisturizers and sunscreens. Today manufacturers make it through a controlled, solvent-free polymerization. The finished polymer is washed, dried and milled into a fine white powder that quickly hydrates when sprinkled into water.

The ingredient shows up in a wide range of leave-on and rinse-off products such as facial serums, anti-aging creams, sheet mask essences, lightweight moisturizers, spot treatments for oily skin, hair gels and even makeup primers. Its job is usually invisible to the eye yet vital to the feel and stability of the formula.

Polyacrylic Acid Crosspolymer’s Cosmetic Benefits/Uses

This ingredient supports the overall performance of a formula in two key ways

  • Emulsion stabilising: It keeps oil and water phases mixed so lotions do not split and active ingredients stay evenly distributed from the first pump to the last
  • Viscosity controlling: It thickens watery blends into silky gels or rich creams allowing brands to fine-tune texture spreadability and cushion without heavy waxes or butters

Who Can Use Polyacrylic Acid Crosspolymer

This polymer is considered friendly to all main skin types including dry, oily, combination, sensitive and mature skin. It sits on the surface and does not pull water out of the skin so it rarely triggers dryness or excess oil production. Because it has an extremely low chance of clogging pores it is generally safe for acne-prone complexions too.

Polyacrylic Acid Crosspolymer is fully synthetic and does not come from animals or animal by-products which makes it suitable for both vegans and vegetarians. It is also free of common food allergens like soy or nuts.

Current data show no specific risks for women who are pregnant or breastfeeding when the ingredient is used topically in cosmetics. That said this is not medical advice and anyone who is expecting or nursing should run all personal care products past a qualified healthcare professional to be safe.

The polymer itself does not make skin more sensitive to sunlight so it will not raise the risk of sunburn. As with any skincare ingredient the overall product formula matters most so keeping normal sun protection habits is still important.

Potential Side Effects/Adverse Reactions

Responses to topical Polyacrylic Acid Crosspolymer can differ from person to person. The points below list potential effects only and most users will not notice any problems when the ingredient is used correctly by the manufacturer.

  • Mild skin irritation a small number of people may feel slight redness or stinging especially on very compromised skin
  • Allergic contact dermatitis rare cases of an allergic reaction have been reported with related acrylic polymers leading to itching rash or swelling
  • Eye irritation on direct contact gels or creams that accidentally enter the eyes can cause temporary burning or watering
  • Respiratory irritation from raw powder more of a workplace issue but breathing in the dry ingredient before it is added to a formula can irritate the nose or throat

If any uncomfortable reaction occurs stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 0/5. Polyacrylic Acid Crosspolymer is a large water-loving molecule that sits on top of the skin and does not mix with skin oils. It creates no greasy film, is not absorbed into pores, and has no record of blocking follicles. Because of this it is considered non-comedogenic and is generally suitable for people who are prone to acne or breakouts.

Keep in mind that the finished product also contains other ingredients. A cream thickened with this polymer could still clog pores if it is loaded with heavy oils or waxes, so always look at the full formula when choosing acne-friendly products.

Summary

Polyacrylic Acid Crosspolymer thickens watery mixes into smooth gels and locks oil and water together so lotions stay stable from first use to last. It does this by swelling in water and forming a flexible three-dimensional net that holds the formula in place.

The polymer is a quiet workhorse in skin and hair care. You will spot it in everything from light serums to sunscreens yet it rarely gets a headline on the front of the pack.

Current safety data show a very low risk of irritation or pore clogging. Still, every skin is different so it is wise to patch test any new product that contains it before using it all over.

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