Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane?

Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane is a silicone-based polymer created by linking dimethyl silsesquioxane units with a chain of polypropylene glycol that ends in a butyl group. The result is a lightweight ingredient that combines the silky slip of silicones with the water-attracting nature of glycols. Silicones first entered beauty labs in the 1950s for their smooth, protective feel. Over time chemists began grafting different side chains onto the silicone backbone to solve specific texture or performance issues. This particular hybrid was developed to give traditional silicones better affinity for both oil and water, making it versatile for modern, multi-benefit formulas.

The manufacturing process starts with siloxane monomers that undergo controlled hydrolysis and condensation to form a cage-like silsesquioxane core. Polypropylene glycol with a butyl end cap is then attached through a series of catalytic reactions. The finished polymer is purified, yielding a clear, low-odor liquid that disperses easily in both water and oil phases.

You will most often spot Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane in rinse-off and leave-in hair products such as shampoos, conditioners, masks, serums and styling creams. It also appears in facial cleansers, lightweight moisturizers and hydrating primers where a soft after-feel is desired.

Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane’s Cosmetic Benefits/Uses

This ingredient pulls triple duty in a formula, adding performance in several key areas:

  • Hair conditioning – coats strands with a breathable film that smooths the cuticle, reduces frizz, boosts shine and makes detangling easier
  • Humectant – attracts and binds water to the surface of hair or skin helping maintain moisture levels for a softer touch
  • Cleansing – lifts away excess oil and impurities while leaving behind a weightless silky finish that prevents the stripped feeling sometimes caused by harsh surfactants

Who Can Use Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane

This ingredient is generally well tolerated by all skin and hair types. Its lightweight texture makes it comfortable for oily or combination skin while its water-binding ability adds welcome moisture for normal and dry skin. Highly sensitive or reactive skin can usually handle it too because the polymer sits on the surface and has very low potential to penetrate or disturb the skin barrier.

Vegans and vegetarians can use products containing Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane. The polymer is produced entirely from synthetic silicones and glycols so no animal-derived raw materials are involved.

The molecule is not known to be absorbed systemically in any meaningful amount which means it is considered low risk for women who are pregnant or breastfeeding. That said this is not medical advice and anyone who is expecting or nursing should review all personal care products with a qualified healthcare professional to be sure they align with individual needs.

Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane does not make skin more sensitive to the sun and has no known interactions with UV filters or self-tanning agents. It is also safe to use alongside common actives such as retinoids alpha hydroxy acids or vitamin C.

Potential Side Effects/Adverse Reactions

Reactions to topical Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane vary from person to person. The issues listed below are possible but uncommon when the ingredient is used at typical levels in a well-formulated product.

  • Mild skin irritation such as redness stinging or itching
  • Contact dermatitis in individuals with a silicone sensitivity
  • Transient eye irritation if the product accidentally migrates into the eyes
  • Potential buildup on very fine or low-porosity hair leading to a weighed-down feel
  • Rare clogged pores in those extremely prone to comedones

If any discomfort or adverse change appears stop using the product and seek advice from a medical professional or pharmacist.

Comedogenic Rating

Rating: 1 / 5 (low)

The molecule is large and sits on the skin surface so it is unlikely to block pores on its own. It forms a breathable film that lets water vapor pass through which further lowers clogging potential. A rating of 1 reflects this low risk while still acknowledging that any occlusive agent can contribute to buildup when layered with heavy oils or used on skin that is not cleansed thoroughly.

Most people prone to acne can comfortably use products containing Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane.

If breakouts occur they are usually linked to the overall formula or inadequate cleansing rather than the polymer itself.

Summary

Polydimethylsiloxy Ppg-13 Butyl Ether Silsesquioxane acts as a hair conditioner, humectant and gentle cleanser all in one. Its silicone backbone delivers slip and cuticle smoothing while the attached polypropylene glycol attracts moisture. The hybrid structure also helps lift away excess sebum without the squeaky feel of stronger surfactants.

It is not yet a household name but formulators appreciate it for adding lightweight softness in next generation hair and skin care so its presence is steadily growing in shampoos, leave-ins and gel-cream moisturizers.

Overall safety data show very low irritation and minimal pore clogging so most users tolerate it well. As with any new product a quick patch test on a small area is a smart way to confirm personal comfort before full use.

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