Polyglyceryl-10 Hexaoleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-10 Hexaoleate?

Polyglyceryl-10 Hexaoleate is a plant based ingredient created by joining ten glycerin units with six molecules of oleic acid, the fatty acid that makes olive oil so skin friendly. This union forms a mild, oil loving compound that is both water dispersible and skin compatible. The raw materials usually come from renewable sources such as coconut, sunflower or rapeseed oils, making it a popular choice for brands that focus on cleaner labels and vegan formulas.

The cosmetic industry began turning to polyglyceryl esters in the early 2000s as a gentler alternative to traditional PEG emulsifiers. Advances in green chemistry made it possible to link glycerin and fatty acids through a simple heat driven esterification process, cutting down on solvents and harsh catalysts. The end result is a biodegradable liquid that slips easily into oil phases and rinses away without residue.

You will often spot Polyglyceryl-10 Hexaoleate in cleansing oils, two phase makeup removers, lightweight moisturizers, leave on masks, baby lotions, sunscreen milks and hair conditioners. Formulators like it because it helps oil and water mix while leaving a soft, non greasy feel on skin and hair.

Polyglyceryl-10 Hexaoleate’s Cosmetic Benefits/Uses

This multitasking ingredient brings a couple of key perks to beauty formulas.

  • Emollient: It spreads easily over the skin filling in tiny surface gaps to smooth rough patches and boost softness. Because it is lightweight it delivers comfort without a heavy or oily after feel making it ideal for daily wear products and summer friendly textures.
  • Emulsifying: Its structure has both water loving and oil loving parts allowing it to pull watery and oily ingredients together into a stable mix. This keeps lotions from separating improves the texture of cleansing oils so they rinse clean and lets brands cut down on stronger surfactants that can strip the skin.

Who Can Use Polyglyceryl-10 Hexaoleate

Thanks to its light texture and mild nature Polyglyceryl-10 Hexaoleate works well for most skin types including dry, oily and combination skin. Sensitive skin usually tolerates it because it is free from harsh solvents and common allergens. Extremely acne prone users may want to watch how their skin reacts since the ingredient is still a fatty ester, though its lightweight character makes breakouts unlikely for the majority.

The raw materials come from plant oils and the production process involves no animal derived substances so products containing Polyglyceryl-10 Hexaoleate are generally suitable for vegans and vegetarians.

No data suggest any specific risks for people who are pregnant or breastfeeding but this is not medical advice. Anyone expecting or nursing should discuss new skincare with a qualified healthcare provider to be extra safe.

The ingredient does not increase photosensitivity and can be used in both day and night formulas without raising the risk of sun related skin damage.

Potential Side Effects/Adverse Reactions

Individual responses to topical Polyglyceryl-10 Hexaoleate can vary. The points below outline possible side effects yet most users will not experience them when the ingredient is included at appropriate levels in a well formulated product.

  • Mild skin irritation such as redness or itching in very sensitive individuals
  • Rare allergic contact dermatitis for those with a specific sensitivity to fatty esters
  • Temporary eye stinging if the product accidentally gets into the eyes
  • Clogged pores or minor breakouts in users who are highly acne prone

If any of these reactions occur stop using the product and seek advice from a healthcare professional

Comedogenic Rating

Rating: 2 / 5

Although Polyglyceryl-10 Hexaoleate is built from oleic acid, its conversion into a large polyglyceryl ester makes it lighter and more water dispersible than straight plant oils. This bulkier structure is less likely to settle into pores yet the oleic backbone still gives it a mild potential to clog in skin that reacts easily. A rating of 2 reflects this low to moderate risk.

Most people, including those prone to breakouts, can use it without problems but highly acne prone users might prefer to monitor their skin for any changes.

The ingredient is typically used at modest levels in finished formulas and is often paired with fast spreading silicones or lightweight esters that further lower any pore clogging tendency.

Summary

Polyglyceryl-10 Hexaoleate acts as an emollient and an emulsifier. Its glycerin sections love water while its oleic parts love oil so it can pull the two together, stabilising lotions and helping cleansing oils rinse off cleanly. At the same time the fatty side smooths rough spots and boosts softness without a greasy after feel.

The ingredient has gained steady popularity in modern skincare because it fits the demand for plant based mild emulsifiers, though it is still less common than classic PEG compounds. You will mainly see it in gentle cleansers, lightweight lotions and baby care products where its mildness shines.

Safety data and decades of use show a very low irritation profile. Serious reactions are rare, making it suitable for most users. As with any new skincare ingredient it is wise to patch test a product that contains Polyglyceryl-10 Hexaoleate first just to be sure it plays nicely with your individual skin.

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