Polyglyceryl-2 Myristate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-2 Myristate?

Polyglyceryl-2 Myristate is an ester formed when diglycerol, a short chain of two glycerin units, reacts with myristic acid, a 14-carbon fatty acid most often sourced from coconut or palm kernel oil. The result is a mild plant-derived ingredient that blends the water loving nature of glycerin with the oil compatible tail of myristic acid. This balance makes it ideal for working at the delicate boundary where water and oil meet inside a cosmetic formula.

The rise of cleaner, more skin-friendly emulsifiers in the 1990s steered formulators toward polyglyceryl esters as an alternative to older petrochemical surfactants. As consumer demand grew for products free of ethoxylated or PEG-based ingredients, Polyglyceryl-2 Myristate gained traction for offering comparable performance while keeping label lists shorter and easier to understand.

Manufacturing involves heating plant-derived glycerin so two molecules join to create diglycerol. This diglycerol is then esterified with myristic acid in the presence of food-grade catalysts, followed by purification to remove any unreacted material. The finished ingredient appears as a soft wax or viscous liquid that readily blends into both oil and water phases.

You will most often find Polyglyceryl-2 Myristate in everyday products such as facial moisturizers, sunscreens, lightweight lotions, creamy cleansers, makeup primers, tinted moisturizers and rinse-off masks where a stable oil-in-water emulsion is critical.

Polyglyceryl-2 Myristate’s Cosmetic Benefits/Uses

Its primary job is to serve as an emulsifier that keeps a formula smooth, stable and pleasant on skin. By positioning itself at the interface of water and oil droplets it prevents separation, reduces the need for heavy surfactants and creates a light elegant texture that spreads easily without leaving a greasy film.

Who Can Use Polyglyceryl-2 Myristate

Because it is a mild, plant-derived emulsifier with a light skin feel, Polyglyceryl-2 Myristate is generally suitable for dry, normal, combination and even oily skin that prefers non-greasy textures. Sensitive skin tends to tolerate it well thanks to the absence of harsh surfactants or solvents, though extremely reactive complexions should still pay attention to the full ingredient list of any product.

The raw materials are typically sourced from vegetable glycerin and coconut or palm kernel oil, so the finished ingredient is appropriate for vegans and vegetarians. If strict cruelty-free standards are important, look for brands that verify their supply chain and avoid animal testing.

Current safety assessments show no specific concerns for women who are pregnant or breastfeeding when Polyglyceryl-2 Myristate is used as intended in cosmetics. This is not medical advice and anyone who is expecting or nursing should run all skincare choices past a qualified doctor just to be on the safe side.

The ingredient does not absorb UV light and is not known to cause photosensitivity, so it will not make skin more prone to sunburn. It is also odourless, which means there is minimal risk of fragrance-related irritation.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Polyglyceryl-2 Myristate can vary from person to person. The following list covers potential reactions but most users will not experience them when the ingredient is formulated and used correctly.

  • Transient stinging or redness in very sensitive skin
  • Mild irritation if used in an overly high concentration or in combination with other irritants
  • Rare cases of allergic contact dermatitis in individuals sensitive to fatty acid esters
  • Possible pore congestion for those highly prone to blemishes if the overall formula is heavy or occlusive

If any unwanted reaction develops stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 out of 5

Polyglyceryl-2 Myristate carries only a single myristic acid tail and is balanced by two glycerin units, so it spreads easily without forming the thick oily film that often clogs pores. The molecule is also used at low levels, further lowering any risk of blockage. For these reasons it sits at the low end of the comedogenic scale.

This makes the ingredient generally suitable for people who are prone to acne or breakouts, provided the overall formula is light and well suited to their skin type.

Real-world reports of clogged pores are scarce, though very oil-rich creams that include this emulsifier could still feel heavy on extremely oily skin.

Summary

Polyglyceryl-2 Myristate is a plant based emulsifier that keeps water and oil mixed, builds a smooth texture and helps products glide on without grease. It works by parking its water loving head in the aqueous phase while its fatty tail anchors into the oil phase, locking the two together so the formula stays homogenous from first pump to last drop.

It is not a blockbuster ingredient you see advertised on the front of every bottle, yet it has a steady presence in clean beauty and sensitive skin lines that need gentle non-PEG emulsifiers.

Safety data shows a low risk of irritation or sensitization when used as intended. Still, each person is different so it is wise to patch test any new product that contains Polyglyceryl-2 Myristate before applying it all over the face.

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