Polyglyceryl-3 Dicocoate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-3 Dicocoate?

Polyglyceryl-3 Dicocoate is a plant-derived ingredient created by linking coconut fatty acids to a short chain of three glycerin molecules. Chemically it is a diester, meaning two fatty acid chains are attached to the polyglycerol backbone. The coconut origin gives it a naturally rich yet lightweight character while the glycerin portion brings water-friendly properties.

Its arrival in cosmetics coincided with the industry’s move toward milder, biodegradable and PEG-free emulsifiers during the early 2000s. Brands looking for a greener alternative to traditional surfactants found that esterifying polyglycerol with coconut oil delivered both gentle feel and reliable performance, so its use quickly spread from niche natural lines to mainstream formulas.

The ingredient is manufactured through a food-grade esterification process. First, glycerin molecules are polymerized to form polyglycerol-3. This is then reacted with purified coconut fatty acids under controlled heat and vacuum, producing a clear to pale yellow liquid that requires no additional solvents.

You can spot Polyglyceryl-3 Dicocoate in a wide range of products such as facial cleansers, makeup-removing balms, hydrating lotions, overnight masks, baby care creams, sunscreens, hair conditioners and anti-aging moisturizers where a gentle oil-in-water blend is desired.

Polyglyceryl-3 Dicocoate’s Cosmetic Benefits/Uses

In formulas this versatile ester mainly serves two important roles:

  • Emollient: It softens skin by forming a breathable film that traps moisture. The coconut-based lipids smooth rough patches, boost suppleness and give products a silky glide without a greasy after-feel.
  • Emulsifying: Its dual water-loving and oil-loving structure lets it bind oils with water, creating stable, uniform creams and lotions. This helps keep textures light, prevents separation and allows brands to lower the amount of heavier surfactants, improving tolerance for sensitive skin.

Who Can Use Polyglyceryl-3 Dicocoate

Thanks to its balanced mix of light coconut lipids and water-friendly glycerin, Polyglyceryl-3 Dicocoate works well for most skin types. Dry and mature skin benefit from the softening film it leaves, while normal and combination skin appreciate the silky glide that is not heavy or greasy. Sensitive skin often tolerates the ingredient since it is free of harsh solvents and common allergens. Extremely oily or very acne-prone skin may want to monitor use, as any fatty acid-based ester could contribute to clogged pores in a small number of cases.

The ingredient is entirely plant sourced, using coconut fatty acids and vegetable glycerin, so it is suitable for both vegans and vegetarians. No animal-derived materials or by-products are involved in its production.

Current research shows no issues for pregnant or breastfeeding women when the ingredient is used as directed in cosmetics. This is not medical advice so anyone who is expecting or nursing should show the full product to a doctor before starting regular use, just to be safe.

Polyglyceryl-3 Dicocoate does not make skin more sensitive to sunlight and has no documented effect on photosensitivity.

Potential Side Effects/Adverse Reactions

Reactions to topical Polyglyceryl-3 Dicocoate differ from person to person. The points below list potential side effects that could occur, though most users will not experience them when the ingredient is formulated and used correctly.

  • Mild skin irritation such as redness itching or a stinging sensation
  • Allergic contact dermatitis in individuals who are sensitive to coconut derivatives
  • Temporary acne flare-ups or clogged pores in very acne-prone skin
  • Eye irritation if the product accidentally gets into the eyes

If you notice any of these issues stop using the product and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 2 / 5

Polyglyceryl-3 Dicocoate is made from coconut fatty acids, which on their own can be pore clogging, but once they are turned into this larger ester the molecule sits more on the skin surface and is less likely to block pores. Most tests and formulator reports place it in the low to moderate range, so it earns a 2. At typical use levels of 1–5% in a finished formula the risk of breakouts is low for many people. Those who are very acne prone should still keep an eye on how their skin responds.

Comedogenicity also depends on the full recipe. When Polyglyceryl-3 Dicocoate is paired with lightweight oils and good cleansing habits its clogging risk drops even further.

Summary

Polyglyceryl-3 Dicocoate acts as a two-in-one helper: it softens skin by laying down a light, silky film and it keeps water and oil blended so creams stay smooth. The glycerin side loves water, the coconut side loves oil, letting it bridge both worlds in a gentle way.

The ingredient is catching on in modern formulas that aim for a cleaner label and a softer feel but it is not yet as common as long-standing emulsifiers like polysorbates. Brands focused on plant based and PEG free claims reach for it more often.

Current safety data shows it is well tolerated with only a small chance of irritation or breakouts for sensitive users. As with any new product though it is smart to do a quick patch test first so you know your own skin’s response.

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