Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether?

Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether is a plant-derived ingredient created by linking three glycerin molecules (polyglyceryl-3) to a small amount of 2-ethylhexyl glycidyl ether, an oil-friendly compound often sourced from fatty acids found in vegetable oils. Chemists developed it in the early 2000s when brands were looking for milder, more environmentally friendly surfactants that could replace traditional sulfates. The manufacturing process involves heating polyglyceryl-3 with a controlled amount of 2-ethylhexyl glycidyl ether so the molecules bond and form a single, multifunctional ingredient that is partly water loving and partly oil loving. Because of this balanced structure it dissolves oils, lifts dirt and helps oil and water blend smoothly.

You will most often spot Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether in micellar waters, gel or cream cleansers, makeup removers, baby washes, lightweight moisturizers, sunscreens, hair conditioners and even sheet masks and anti-aging serums that rely on gentle cleansing action during rinsing.

Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether’s Cosmetic Benefits/Uses

This ingredient boosts a formula in more than one way:

  • Cleansing: Its surfactant nature grabs on to oil and grime while staying mild on skin so it washes away makeup, sunscreen and daily buildup without leaving a tight or squeaky feel
  • Emulsifying: It helps water based and oil based ingredients mix evenly which gives lotions and washes a smooth, stable texture and stops products from separating on the shelf

Who Can Use Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether

This ingredient is considered gentle and non stripping so it suits most skin types, including dry, oily, combination and sensitive skin. Because it has a mild cleansing action and does not leave residue it rarely aggravates acne prone skin. People with very reactive or allergy prone skin should still check the full ingredient list of any product to ensure there are no added fragrances or other triggers.

Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether is produced from vegetable derived glycerin and plant based fatty acids. No animal matter or by products are involved, making it suitable for vegans and vegetarians.

No data suggests that this ingredient poses a risk during pregnancy or while breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should review new skincare products with a qualified healthcare professional to be safe.

The molecule itself does not make skin more sensitive to sunlight and it has no known photosensitizing effects. It is also odorless so it will not clash with fragrance sensitive users. As it is biodegradable and derived from renewable feedstocks, people looking for greener options often appreciate its inclusion.

Potential Side Effects/Adverse Reactions

Reactions to topical Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether vary from person to person. The points below outline potential side effects only and most users will not experience them when the ingredient is used correctly in a well formulated product.

  • Skin irritation in the form of redness or stinging, usually when used in very high concentrations or on already compromised skin
  • Contact dermatitis in rare cases where an individual is allergic to the molecule or another component in the formula
  • Eye irritation if a concentrated product like a cleanser is allowed to sit in the eye area without rinsing

If you notice persistent discomfort, redness or swelling after applying a product containing this ingredient discontinue use and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 1 / 5

Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether earns a very low score because it is highly water compatible and designed to rinse away without leaving an oily film that could clog pores. Its molecule is large enough to sit on the surface only briefly and it has no heavy plant oils or waxes attached. For these reasons it is generally safe for people who are prone to acne or breakouts.

Because the ingredient is most often found in cleansers that are washed off within a minute, any residue left behind is minimal which further reduces the chance of blockage. At the same time it can help loosen sebum and makeup so they rinse away more completely, another plus for congested skin.

Summary

Polyglyceryl-3 Hydroxypropyl Ethylhexyl Ether is a gentle multitasker that cleanses skin and hair while acting as an emulsifier to keep oil and water mixed smoothly. It works by using its water loving glycerin side to grab onto grime and its oil loving ethylhexyl side to dissolve makeup and sebum, allowing everything to rinse away cleanly.

The ingredient is gaining popularity in modern sulfate-free formulas but is still less common than long-standing surfactants like coco-glucoside or sodium laureth sulfate. Brands looking for gentler and more eco-friendly options are adopting it in micellar waters, cream cleansers and baby products.

Safety data show it is low risk for irritation or sensitization when used at normal levels. That said every skin type is unique so it is always wise to do a quick patch test with any new product that contains this or any other unfamiliar ingredient just to be safe.

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