Polyglyceryl-3 Olivate Phosphate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-3 Olivate Phosphate?

Polyglyceryl-3 Olivate Phosphate is a plant-derived ingredient made by joining three distinct pieces: polyglycerin-3, fatty acids from olives and a small amount of phosphoric acid. The result is a gentle, biodegradable compound that acts a bit like a soap molecule, with one end that likes water and another that likes oil. Although olives have been used in skin care for centuries, this modern derivative appeared only in the last decade as brands searched for alternatives to petroleum-based surfactants. Manufacturers create it through a two-step esterification process. First, glycerin obtained from vegetable oils is polymerized into polyglycerin-3. That chain is then reacted with olive fatty acids to form polyglyceryl-3 olivate, which finally undergoes phosphorylation. The finished ingredient is a mild, palm-free surfactant that fits clean beauty standards. You will most often spot it in gel cleansers, creamy face washes, micellar waters, lightweight lotions, sunscreens, baby products and natural hair conditioners where formulators want a soft feel without sulfates.

Polyglyceryl-3 Olivate Phosphate’s Cosmetic Benefits/Uses

This multitasker brings more than one useful role to a formula

  • Cleansing: Its water-loving and oil-loving ends help lift away dirt, makeup and excess sebum while keeping the skin’s natural barrier comfortable, so products rinse clean without tightness
  • Emulsifying: It binds oil and water into a stable mixture, allowing creams, milks and lotions to stay smooth over time and giving finished products a light, non-greasy feel

Who Can Use Polyglyceryl-3 Olivate Phosphate

This ingredient is generally well tolerated by all skin types, including dry, oily, combination and sensitive skin, because it cleanses without stripping the natural lipid barrier. Extremely reactive or allergy-prone skin should still proceed cautiously, as with any new ingredient, but there is no specific skin type that should routinely avoid it.

Polyglyceryl-3 Olivate Phosphate is plant derived, with its building blocks sourced from vegetable glycerin and olive fatty acids, and contains no animal by-products or animal testing requirements, so it fits vegan and vegetarian standards.

Current safety data show no link between this ingredient and issues in pregnancy or breastfeeding. That said this information is educational only and not medical advice, so anyone pregnant or nursing should confirm product choices with a qualified healthcare professional.

The molecule does not absorb UV light and is not known to make skin more sensitive to the sun. It is also fragrance free and gluten free, two points of interest for people monitoring those factors.

Potential Side Effects/Adverse Reactions

Responses to topical Polyglyceryl-3 Olivate Phosphate can vary from person to person. The points below outline potential side effects yet most users will not experience them when the ingredient is formulated and used correctly.

  • Mild skin irritation such as redness or itching
  • Transient stinging if the product gets into the eyes
  • Allergic contact dermatitis in individuals sensitive to olive derivatives or glycerin polymers
  • Dryness or tightness if used in a formula with a very high surfactant load

If you notice any discomfort or irritation while using a product containing Polyglyceryl-3 Olivate Phosphate discontinue use and consult a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5 (very low)

Polyglyceryl-3 Olivate Phosphate is built from large, water-loving and oil-loving segments that tend to stay on the surface of the skin and rinse away rather than sinking into pores. It is used at low levels in most formulas and breaks down easily in water so it is unlikely to trap sebum or dead cells inside follicles. With this low comedogenic profile it is generally suitable for people prone to acne or breakouts.

As with any surfactant the finished product matters: if the formula also contains heavy oils or waxes the overall pore-clogging potential can rise, so always judge the full ingredient list rather than a single component.

Summary

Polyglyceryl-3 Olivate Phosphate acts mainly as a gentle cleanser and an emulsifier. Its dual nature lets it grab onto both oil and water which helps lift away grime while holding oil and water together in stable mixtures, giving cleansers a mild lather and creams a smooth, lightweight feel.

The ingredient is gaining popularity in eco-focused and sensitive-skin lines but it is still less common than traditional sulfates or PEG emulsifiers. Brands that spotlight plant-based sourcing and biodegradable profiles are bringing it to a wider audience.

Current data show it to be a safe option for most users with low irritation and a very low chance of clogging pores. Still, skin can be unpredictable so doing a quick patch test when trying any new product is a smart habit.

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