Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone?

Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone is a hybrid silicone made by linking a water-loving polyglycerin chain to a traditional dimethicone backbone. The polyglycerin part helps it blend with water while the silicone part delivers the smooth slip many people associate with silicons. It is created through a controlled reaction where glycerin units are first connected into a short chain then grafted onto a modified dimethicone segment. The result is a large yet lightweight molecule that sits on the surface of skin or hair forming a thin flexible film.

Synthesized in the late 1990s as formulators searched for silicones that rinse off more easily, this ingredient quickly found a place in leave-on and rinse-off products. Its balance of oil-loving and water-loving sections lets it spread without the heavy feel some older silicones can leave behind. Today it is made in modern facilities that combine glycerin sourced from vegetable oils with medical-grade siloxane units under heat and vacuum, then purify the finished polymer to cosmetic-grade standards.

You will most often spot Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone in lightweight moisturizers, priming serums, anti-aging creams, hair masks, color-safe conditioners and frizz-taming blow-dry sprays. It is also used in sunscreens and long-wear makeup where it helps pigment stay put while keeping the formula comfortable.

Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone’s Cosmetic Benefits/Uses

This versatile ingredient offers more than one beauty benefit

  • Hair Conditioning: Forms a breathable film around each strand that smooths cuticles, boosts shine and helps detangle without weighing hair down. It also shields against heat and humidity making styles last longer.
  • Skin Conditioning: Glides over the skin filling in tiny gaps so the surface feels softer and looks more even. The light film helps lock in moisture, reduces water loss and leaves a silky finish that improves makeup wear.

Who Can Use Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone

This silicone-glycerin hybrid is generally well tolerated by every skin type. Dry and mature skin benefit from its moisture-holding film while oily or combination skin appreciates its featherlight feel that will not clog pores. Sensitive skin usually handles it well because the molecule sits on the surface rather than penetrating deeply; however anyone with a known silicone allergy should approach with caution.

The ingredient is synthesized from vegetable-derived glycerin and lab-made silicones so it contains no animal by-products. That makes it suitable for both vegans and vegetarians when sourced from suppliers that follow cruelty-free standards.

No research indicates that topical use poses a risk during pregnancy or breastfeeding. Still this is not medical advice and pregnant or nursing individuals should have a healthcare professional review any product they plan to use.

Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone is non-photosensitizing and will not increase sun sensitivity. It also plays nicely with other common skincare actives so layering it in a routine is uncomplicated.

Potential Side Effects/Adverse Reactions

Responses to topical Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone differ from person to person. The effects listed below are only potential outcomes; most people experience none of them when the ingredient is used correctly in a well-formulated product.

  • Mild skin irritation or transient redness in very reactive skin
  • Contact dermatitis in individuals with a silicone sensitivity
  • Eye irritation or watering if a leave-on product migrates into the eyes
  • Build-up on hair making strands feel coated if cleansing is insufficient

If any discomfort or adverse reaction occurs stop using the product and consult a qualified healthcare professional for guidance.

Comedogenic Rating

Rating: 1 / 5

Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone is a large molecule that mostly stays on the surface of skin instead of seeping into pores. Its slick silicone backbone helps it glide while the attached polyglycerin chain keeps the finish light and water compatible, reducing the risk of pore blockage. Tests and user feedback rarely link it to breakouts which is why it earns a low score of 1.

That makes it generally suitable for people who are prone to acne or congestion, especially when used in well balanced formulas that rinse off cleanly.

Keep in mind that overall product texture, presence of heavy oils and cleansing habits can influence how any ingredient behaves, so the full formula still matters.

Summary

Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone conditions skin and hair by forming a thin flexible film that smooths rough spots locks in moisture and boosts slip. Its silicone part delivers the familiar silky feel while the polyglycerin side improves spreadability and helps the ingredient rinse away more easily than classic dimethicone.

Though not as famous as dimethicone or cyclopentasiloxane, it is steadily gaining ground among formulators who want a lighter silicone with better water affinity. You will see it most in modern moisturizers, primers and lightweight conditioners.

Current data shows it is very safe for topical use with low irritation and comedogenic potential. As with any new cosmetic it is smart to perform a small patch test first to be sure your skin agrees before applying it all over.

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