Polyglyceryl-4 Polyricinoleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-4 Polyricinoleate?

Polyglyceryl-4 Polyricinoleate is an ester that joins together two naturally occurring building blocks. The first part is polyglycerol, a small cluster of glycerin units often made from plant oils. The second part is a polymer of ricinoleic acid which comes from castor oil. When these pieces are combined through a controlled heating and vacuum process called esterification they form a silky liquid that mixes oil and water with ease.

The ingredient was first developed for the food industry to keep cocoa butter and other fats from separating in chocolate. Its strong ability to hold oily and watery phases together soon caught the eye of cosmetic chemists in the late twentieth century. Since then it has become a regular helper in beauty labs around the world.

Polyglyceryl-4 Polyricinoleate is made by reacting polyglycerol with ricinoleic acid in the presence of heat and a catalyst. The result is filtered and purified so the final product is gentle on skin and stable on the shelf.

You are most likely to see this ingredient in products that need to stay smooth and uniform: moisturizers, sunscreens, cleansing balms, masks, lipsticks, foundations and creamy serums. It is especially helpful in water-in-oil or high oil content formulas where lesser emulsifiers can struggle.

Polyglyceryl-4 Polyricinoleate’s Cosmetic Benefits/Uses

The main job of Polyglyceryl-4 Polyricinoleate in skin care and makeup is emulsifying. It keeps oily ingredients and watery ingredients bound together so a product stays even from the first scoop to the last drop. A stable emulsion feels nicer on the skin spreads more easily and delivers active ingredients in a uniform way which boosts product performance and user satisfaction.

Who Can Use Polyglyceryl-4 Polyricinoleate

This emulsifier is considered gentle enough for almost every skin type. Dry skin benefits from the smooth, cushiony feel it lends to rich creams while oily and combination skin appreciate the lightweight spread that does not clog pores. Sensitive skin generally tolerates it well because it is nonionic and free of common irritants. There are no specific skin types that need to avoid it unless an individual has a unique sensitivity to castor oil derivatives.

Polyglyceryl-4 Polyricinoleate is suitable for vegans and vegetarians. Both glycerin units and ricinoleic acid are sourced from plants, most often non-GMO vegetable oils and castor beans, so no animal-derived material is involved.

Current safety assessments show no issues for pregnant or breastfeeding women when this ingredient is used topically in cosmetics. It is not known to penetrate deeply or build up in the body, still this is not medical advice and anyone who is pregnant or nursing should clear all skincare products with a qualified healthcare provider.

The ingredient does not make skin more sensitive to sunlight and has no known interactions with sunscreen filters, so normal sun habits apply.

Potential Side Effects/Adverse Reactions

Side effects from topical use of Polyglyceryl-4 Polyricinoleate differ from person to person. The points below list potential reactions yet they are rare when the ingredient is used at typical cosmetic levels and formulated correctly.

  • Mild skin irritation such as redness or itching in very sensitive users
  • Allergic contact dermatitis in individuals allergic to castor oil derivatives
  • Temporary eye stinging if a product containing the ingredient gets into the eyes
  • Occasional clogged pores in users highly prone to acne when used in heavy, oil-rich formulas

If any discomfort, rash or worsening of breakouts occurs stop using the product and seek advice from a medical professional.

Comedogenic Rating

Rating: 1 / 5

Polyglyceryl-4 Polyricinoleate is a large, water-loving molecule that tends to sit on the skin surface rather than slipping into pores. It is also used at fairly low levels in formulas, so the chance of it blocking follicles is small. The only time breakouts might pop up is when the ingredient is part of a very rich balm or butter that already leans heavy on the skin.

Most people prone to acne can use products containing this emulsifier without extra worry.

If a formula pairs it with high levels of waxes or thick oils, the overall product may feel more occlusive which could increase the risk of congestion for some users.

Summary

Polyglyceryl-4 Polyricinoleate is an effective plant-derived emulsifier that keeps oil and water phases blended so lotions, creams and makeup stay smooth and spreadable. Its structure offers both oil-friendly and water-friendly sections, letting it sit at the interface of the two and lock them together.

While it is not the most headline-grabbing cosmetic star, chemists reach for it often because it works reliably in challenging high-oil systems, is vegan friendly and has a mild skin profile.

Current safety data rate it as low risk with minimal irritation potential, yet it is always smart to patch test any new product to be sure your skin agrees with the full formula.

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