Polyglyceryl-6 Pentaricinoleate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
Share:
Inside this article:

We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polyglyceryl-6 Pentaricinoleate?

Polyglyceryl-6 Pentaricinoleate is a plant-derived ingredient made by linking six glycerin molecules together then attaching five molecules of ricinoleic acid, the fatty acid that naturally occurs in castor oil. This creates a pentaester that is both oil loving and water friendly, giving it a balanced character that skin care chemists value. The material first gained traction in the 1990s when brands began searching for alternatives to petroleum based emulsifiers and chose safer, biodegradable options sourced from food grade oils. To produce it, manufacturers heat purified glycerin until the molecules join into a chain called hexaglycerol, then react that chain with ricinoleic acid in the presence of a food safe catalyst. The result is a waxy liquid that disperses easily in oils and melts on contact with skin.

You will often see Polyglyceryl-6 Pentaricinoleate in rich face creams, water-free balms, cleansing oils, makeup removers, tinted moisturizers, stick foundations and even some sheet mask essences. Formulators pick it when they want a smooth feel without heavy silicones and when they need to keep oil and water phases blended over the product’s shelf life.

Polyglyceryl-6 Pentaricinoleate’s Cosmetic Benefits/Uses

This ingredient pulls double duty in many formulas

  • Emollient: Softens and smooths the skin surface so products glide on easily and leave a comforting, non-greasy finish
  • Emulsifying agent: Helps blend water and oil into a stable mixture which keeps creams from separating, improves texture and ensures each application delivers consistent moisture and active ingredients

Who Can Use Polyglyceryl-6 Pentaricinoleate

This ingredient is generally well tolerated by all skin types, including dry, normal, combination and even sensitive skin because it is free of common irritants like fragrances and essential oils. Those with very oily or acne prone skin can usually still use it, although the rich fatty acid content means extremely blemish prone users might prefer lighter formulas.

Polyglyceryl-6 Pentaricinoleate is derived from plant glycerin and castor oil so it is suitable for vegans and vegetarians. No animal sources or animal testing are required to produce the raw material.

Pregnant and breastfeeding women can use products containing this emulsifier as it is not known to penetrate deeply or disrupt hormones. This is not medical advice and anyone who is pregnant or nursing should run all skincare choices past a qualified healthcare provider to be safe.

The ingredient does not make skin more sensitive to sunlight and has no known interactions with UV exposure, self-tanners or common actives like vitamin C or retinol.

Potential Side Effects/Adverse Reactions

Side effects from topical use vary from person to person. The points below outline potential reactions only and most users will not experience them when the ingredient is used correctly in a well-formulated product.

  • Mild redness or warmth shortly after application
  • Itching or slight stinging in very sensitive skin
  • Rare allergic contact dermatitis for individuals sensitive to castor oil derivatives
  • Occasional clogged pores or small breakouts in extremely oily skin when used in heavy concentrations
  • Temporary eye irritation if the product accidentally gets into the eyes

If any of these effects occur stop using the product and seek advice from a dermatologist or healthcare professional.

Comedogenic Rating

Rating: 1 out of 5

Although it contains fatty acids from castor oil, the polyglyceryl backbone keeps the molecule largely water dispersible which limits its tendency to sit in pores and harden. Most formulators use it at low levels for stability rather than as a heavy occlusive so the chance of pore blockage is low for the average user. In very rich balms or cleansing oils the percentage can climb which may tip the scale for those who clog easily.

Suitable for acne-prone skin in most leave-on and rinse-off products but people who break out at the slightest hint of oil may prefer lighter alternatives.

As with any castor oil derivative, pairing it with highly comedogenic butters or waxes could raise the overall product rating so the full formula matters as much as the raw material itself.

Summary

Polyglyceryl-6 Pentaricinoleate works as a two-in-one helper that softens the skin surface and keeps water and oil happily blended. Its glycerin chain attracts a hint of moisture while its castor-derived tails dissolve easily into oils, giving creams and balms a smooth spread and long-term stability.

You will spot it in a growing lineup of indie moisturizers, cleansing oils and makeup sticks because brands like its plant origin and silicone-free glide. It is not the most famous name on an ingredient deck yet its eco-friendly label appeal and dependable performance are earning it steady fans.

Overall safety is high with low irritation reports and a minimal comedogenic score, making it a comfortable choice for most skin types. Still, everyone’s skin is unique so it is wise to patch test any new product that contains this ingredient before slathering it on daily.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search