Polysorbate 81: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Polysorbate 81?

Polysorbate 81 is a liquid surfactant made by combining sorbitol, a sugar alcohol from fruits and corn, with oleic acid from vegetable oils then attaching chains of ethylene oxide. The result is a nonionic compound that mixes easily with both water and oil. First introduced in the 1950s as a food additive, it soon found a place in personal care products because of its gentle surface activity and stability. Production starts with sorbitol that is dehydrated to form sorbitan, esterified with oleic acid to create sorbitan oleate, then ethoxylated to reach the desired level of water solubility. You will meet Polysorbate 81 in face cleansers, micellar waters, moisturizers, sheet masks, exfoliating gels, lightweight serums, sunscreens, liquid foundations, hair conditioners and scalp tonics.

Polysorbate 81’s Cosmetic Benefits/Uses

This ingredient supports formulas in two key ways:

  • Cleansing: Lowers surface tension so oils, sweat and dirt lift away from skin or hair when rinsed leaving a fresh comfortable feel without harshness
  • Emulsifying: Keeps water and oil phases blended which prevents separation, improves texture, boosts spreadability and helps active ingredients distribute evenly

Who Can Use Polysorbate 81

Thanks to its mild nonionic nature Polysorbate 81 is generally well tolerated by all skin types including dry, oily, combination and sensitive skin. Those with very reactive or broken skin barriers should still monitor for any signs of stinging since even gentle surfactants can sometimes aggravate compromised areas.

The ingredient is produced from plant-derived sorbitol and vegetable-sourced oleic acid with no animal by-products involved, making it suitable for both vegans and vegetarians.

Current safety assessments show no specific risks for people who are pregnant or breastfeeding when Polysorbate 81 is used in rinse-off or leave-on cosmetics. This is not medical advice and anyone expecting or nursing should discuss all skincare choices with a qualified doctor just to be safe.

Polysorbate 81 does not cause photosensitivity so it will not make skin more prone to sunburn. It also plays well with most common cosmetic actives and preservatives.

Potential Side Effects/Adverse Reactions

Individual responses to topical Polysorbate 81 can vary. The following is a list of potential but uncommon side effects. When the ingredient is used at typical cosmetic levels most people do not experience these issues.

  • Mild skin irritation: Slight redness or tingling can occur in very sensitive users especially if the product stays on the skin for extended periods
  • Contact allergy: Rare cases of allergic dermatitis have been reported usually identified by itching rash or small bumps
  • Eye irritation: May cause stinging or watering if a formula accidentally gets into the eyes
  • Increased dryness: High concentrations may strip natural oils leading to a tight or flaky feel
  • Breakouts in acne-prone skin: Though low comedogenic some users notice clogged pores when multiple oily ingredients are present alongside Polysorbate 81

If any of these reactions develop discontinue use and seek guidance from a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 on the 0-5 scale

Polysorbate 81 is largely water soluble once blended into a formula and does not build up inside pores. Its molecules are designed to surround oils then rinse away which limits the chance of residue that could block follicles. Because it is used in low concentrations and has a lightweight texture formulators rely on it even in products labeled non-comedogenic. People who are prone to acne or breakouts can normally use it without issue. Only when a product also contains heavy occlusive oils or waxes might the overall formula feel too rich for very oily skin.

If you notice congestion while using a product that contains Polysorbate 81 look at the full ingredient list since another component is often the real culprit.

Summary

Polysorbate 81 is a plant-derived surfactant that acts as both a gentle cleanser and a reliable emulsifier. It lowers surface tension so grime lifts away and it locks oil and water phases together which keeps creams stable and silky. Although not as famous as glycerin or hyaluronic acid it appears in a wide range of cleansers serums sunscreens and makeup where it quietly does the heavy lifting behind the scenes.

Current safety reviews rate it low risk with irritation and allergy reported only rarely at the levels used in cosmetics. As with any new skincare product it is smart to perform a quick patch test to confirm compatibility with your unique skin.

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