Potassium C12-14 Alkyl Phosphate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Potassium C12-14 Alkyl Phosphate?

Potassium C12-14 Alkyl Phosphate is a mild surfactant created when synthetic fatty alcohols that contain 12 to 14 carbon atoms react with phosphoric acid and are then neutralized with potassium hydroxide. The result is a potassium salt that carries both water-loving and oil-loving parts, allowing it to lift away dirt and oil while staying gentle on skin. Phosphate-based surfactants first appeared in personal care formulas in the mid-20th century as formulators looked for alternatives to traditional soaps that could perform well in hard water while minimizing irritation. Today this ingredient is produced in modern facilities where the fatty alcohols are synthesized from petrochemical feedstocks or renewable plant oils, esterified with phosphoric acid, then carefully purified to meet cosmetic-grade standards.

Because it offers effective yet mild cleansing, Potassium C12-14 Alkyl Phosphate shows up in foaming facial cleansers, micellar waters, shower gels, shampoos, baby washes, makeup remover wipes, exfoliating masks and even some light moisturizers where a touch of rinse-off cleansing is desired.

Potassium C12-14 Alkyl Phosphate’s Cosmetic Benefits/Uses

This ingredient plays a single but important role in formulations

Cleansing: Its amphiphilic structure allows it to surround oil, makeup and daily grime so they can be rinsed away with water. Compared with harsher sulfates it provides a softer, creamier lather and tends to leave skin feeling less stripped which makes it suitable for sensitive skin products, baby care formulas and daily facial cleansers.

Who Can Use Potassium C12-14 Alkyl Phosphate

Thanks to its mild nature Potassium C12-14 Alkyl Phosphate works for most skin types including oily, combination, normal and sensitive skin. Very dry or compromised skin may still prefer formulas that pair the surfactant with richer emollients to avoid any feeling of tightness after cleansing.

The ingredient is synthesized from petrochemical or plant-derived fatty alcohols and contains no animal by-products so it is generally suitable for vegans and vegetarians. As always check the full ingredient list of the finished product since other components might not meet vegan standards.

No data suggest problems for women who are pregnant or breastfeeding when the ingredient is used in rinse-off amounts typically found in personal care products. That said this is not medical advice and anyone expecting or nursing should run their skincare routine past a qualified doctor to be on the safe side.

Potassium C12-14 Alkyl Phosphate does not cause photosensitivity so it will not make skin more prone to sunburn. It is also colorless and odorless so it rarely interferes with fragrance or dye sensitivities.

Potential Side Effects/Adverse Reactions

Reactions to topical Potassium C12-14 Alkyl Phosphate vary from person to person. The following is a list of potential side effects which remain unlikely for most users provided the ingredient has been formulated and used correctly.

  • Mild skin irritation such as redness or itching especially on very sensitive or broken skin
  • Transient dryness or tightness if the cleanser is left on too long or not followed with moisturizer
  • Eye stinging when the product accidentally gets into the eyes
  • Allergic contact dermatitis a rare immune response that shows up as a rash or swelling
  • Scalp irritation or flaking in shampoos for individuals with highly reactive scalps

If any negative reaction occurs stop using the product and seek advice from a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5

Potassium C12-14 Alkyl Phosphate is a water-soluble surfactant that rinses off cleanly and leaves little residue on skin. It has no oily or waxy backbone that can lodge in pores which keeps the clogging risk low. Because it is usually used in wash-off products that spend only seconds on the face its chance of provoking blackheads or pimples is minimal.

Suitable for acne-prone and breakout-prone skin.

Formulas that pair this ingredient with heavy oils or butters could change the overall pore-clogging profile so look at the whole ingredient list if you are very sensitive.

Summary

Potassium C12-14 Alkyl Phosphate is mainly a cleanser. Its dual water-loving and oil-loving structure wraps around dirt makeup and excess sebum so they can be lifted away with water leaving skin clean yet less stripped than harsher sulfates.

You will spot it in everyday face washes baby shampoos micellar waters and the occasional lightweight lotion. It is not a headline star like hyaluronic acid or vitamin C but formulators reach for it when they need a gentle stable surfactant.

Safety data show it is low in irritation potential at the levels found in rinse-off products. While most people can use it without trouble it is smart to patch test any new product to rule out personal sensitivities.

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