Ppg-4-Ceteth-5: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: July 1, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Ppg-4-Ceteth-5?

Ppg-4-Ceteth-5 is a man-made ingredient created by linking small units of propylene oxide and ethylene oxide to a fatty alcohol derived from cetyl (a 16-carbon chain often sourced from coconut or palm). Chemically it is known as an oxirane polymer with a hexadecyl ether backbone. The blend of a water-loving (polyether) side and an oil-loving fatty chain gives it surface-active properties that are useful in skin care.

The technology behind these polyether-fatty alcohol hybrids dates to mid-20th-century research on non-ionic surfactants. As cosmetic chemists looked for gentler cleansers and improved emulsifiers, they adapted industrial grade polyoxypropylenes and polyoxyethylenes to personal care needs. Ppg-4-Ceteth-5 emerged from this effort and has been used in lotions and creams for several decades.

Production involves first polymerizing propylene oxide to create a short polypropylene glycol segment of four repeating units. This segment is then reacted with ethylene oxide to add five ethoxy groups, followed by attachment to cetyl alcohol under controlled conditions. The final liquid or soft wax is purified and quality-checked before it goes to cosmetic labs.

You will most often see Ppg-4-Ceteth-5 in facial cleansers, micellar waters, lightweight moisturizers, sheet mask serums and rinse-off masks where gentle cleansing and a soft finish are desired. It may also show up in body washes and baby care products that aim for mildness.

Ppg-4-Ceteth-5’s Cosmetic Benefits/Uses

This versatile ingredient supports formulas in two main ways:

  • Skin conditioning: Its fatty tail lays down a thin layer that smooths and softens the skin surface leaving it feeling supple rather than stripped after cleansing
  • Cleansing: The balanced water-and-oil structure lifts away dirt, sebum and makeup while maintaining skin comfort making it suitable for gentle daily washes

Who Can Use Ppg-4-Ceteth-5

Ppg-4-Ceteth-5 is generally well tolerated by most skin types, including dry, oily, combination and sensitive skin, because its non-ionic nature cleans without harsh stripping. Extremely delicate or compromised skin that reacts to any surfactant might still prefer formulations with minimal cleansing agents so monitoring comfort levels is advised.

The ingredient is synthesized entirely from petrochemical building blocks and plant-derived cetyl alcohol, with no animal origin or by-products, so it aligns with vegan and vegetarian preferences. Always check the full product label to confirm there are no other animal-derived additives.

No evidence suggests that topical use poses specific risks for pregnant or breastfeeding women when included at normal cosmetic levels. This information is educational only and not medical advice; anyone who is pregnant or nursing should run their skincare choices past a qualified health professional to be safe.

Ppg-4-Ceteth-5 does not increase photosensitivity, so it will not make skin more prone to sunburn. Standard sun protection practices remain recommended when spending time outdoors.

Potential Side Effects/Adverse Reactions

Individual responses to any cosmetic ingredient can differ. The points below outline possible but uncommon reactions to Ppg-4-Ceteth-5 in properly formulated products; most people will not experience them.

  • Mild transient stinging on very sensitive or broken skin
  • Temporary redness or tightness if used in a high-foaming cleanser on already dry skin
  • Contact dermatitis in rare cases of personal sensitivity to polyether surfactants

If irritation, redness or any discomfort develops discontinue use and consult a dermatologist or healthcare provider.

Comedogenic Rating

Rating: 1 out of 5. Ppg-4-Ceteth-5 is a lightweight non-ionic surfactant with a small fatty portion and a sizeable water-loving segment, so it tends to rinse clean without leaving a heavy film that could clog pores. Its molecular size and high solubility further limit the chance of buildup inside follicles.

Because of this low rating, the ingredient is generally fine for people who are prone to acne or breakouts.

Formulation still matters: if the finished product contains rich oils or waxes the overall pore-clogging potential can rise, but Ppg-4-Ceteth-5 itself is unlikely to be the culprit.

Summary

Ppg-4-Ceteth-5 conditions skin and provides gentle cleansing by pairing an oil-compatible cetyl chain with short polyether sections that mix readily with water. This dual nature lifts away grime while leaving a soft, smooth after-feel.

It appears in mainstream facial cleansers, micellar waters and light lotions but is not a headline ingredient, so it flies under the radar compared with trendier actives.

Safety data and decades of use show it is well tolerated for most skin types with a very low risk of irritation or pore blockage. As with any new skincare product, patch testing a small area first is a smart way to confirm personal compatibility.

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