Sodium Bisulfite: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Sodium Bisulfite?

Sodium bisulfite, also known as sodium hydrogen sulfite, is a white crystalline powder derived from the reaction of sulfur dioxide gas with a sodium base such as sodium carbonate or sodium hydroxide. Chemically, it is classified as a sulfite salt and carries reducing properties that make it useful in a range of household and industrial applications. Its journey into cosmetics dates back to the early days of commercial hair treatments when formulators noticed its ability to soften hair bonds safely and predictably. Today manufacturers produce cosmetic-grade sodium bisulfite in controlled reactors where sulfur dioxide is bubbled through a purified sodium solution then dried and milled to a consistent particle size.

Because of its stability and versatility you will often see sodium bisulfite on ingredient labels for rinse-off and leave-on products alike. Common examples include permanent wave lotions, hair relaxers, color-protect shampoos, anti-aging serums that aim to fight oxidation, sheet masks, hydrating creams and multi-purpose preservative boosters used in water-based formulations.

Sodium Bisulfite’s Cosmetic Benefits/Uses

This ingredient supports several goals in personal care formulas

  • Antioxidant: Sodium bisulfite neutralizes oxygen and free radicals that can degrade delicate oils, fragrances and active ingredients helping a product stay fresh and effective for longer
  • Hair Waving or Straightening: In chemical texture services it helps break and reform disulfide bonds inside the hair shaft allowing stylists to create curls or smooth strands without excessive damage
  • Preservative: Its ability to lower microbial growth supports the main preservative system making products safer during their shelf life especially in water-rich creams and gels
  • Reducing agent: As a mild reducer it stabilizes colorants prevents unwanted browning in formulas and assists in maintaining the intended shade of tinted products

Who Can Use Sodium Bisulfite

Sodium bisulfite is generally considered suitable for all skin types including oily, dry, combination and normal because it is usually present at low levels and gets rinsed off or buffered within a balanced formula. Those with very sensitive or compromised skin should still pay extra attention since any sulfite can sometimes trigger irritation if the barrier is already weakened.

The ingredient is mineral derived so it is appropriate for vegans and vegetarians. No animal-based raw materials or by-products are involved in its production.

Pregnant or breastfeeding women are not known to be at special risk when using personal care products that contain sodium bisulfite but this is not medical advice. Anyone who is expecting or nursing should show the full ingredient list to a trusted health professional before adding a new product to their routine just to be safe.

Sodium bisulfite does not make skin more sensitive to the sun and there are no reports linking it to photosensitivity. It also plays well with most other common cosmetic ingredients so routine daytime use followed by normal sun protection is fine.

Potential Side Effects/Adverse Reactions

Side effects and reactions to topical sodium bisulfite can vary from person to person. The points below list potential issues yet most users will not experience them when the ingredient is used correctly in a finished product.

  • Mild stinging or redness on very sensitive skin
  • Contact dermatitis in individuals with a known sulfite allergy
  • Temporary dryness if used in high concentration leave-on formulas
  • Eye irritation if the product accidentally gets into the eyes
  • Unwanted hair color shift or brittleness if over-processed during salon chemical services

If any irritation or other negative effect occurs stop using the product and consult a qualified healthcare professional or dermatologist

Comedogenic Rating

Rating: 0/5

Sodium bisulfite is a small water-soluble salt that rinses away easily and does not leave an oily film on the skin, so it does not block pores. Because clogged pores are what usually trigger breakouts, sodium bisulfite earns a 0 out of 5 on the comedogenic scale.

This makes the ingredient generally suitable for people who are prone to acne or breakouts.

Its low use levels in most formulas and quick rinse-off in hair or cleansing products further reduce any pore-clogging risk.

Summary

Sodium bisulfite works as an antioxidant that shields formulas from oxygen, a mild reducing agent that keeps colors true, a preservative booster that helps control microbes and a hair processing helper that loosens and reforms bonds for waving or straightening. It does these jobs by donating electrons, lowering pH just enough to slow bugs and gently breaking chemical links in hair without heavy damage.

The ingredient is not exactly a household name in skin care but it is a steady performer behind the scenes in many hair solutions, color-stay products and shelf life boosters. Brands use it when they want reliability at a low cost.

Overall safety is high when used at the small percentages allowed in cosmetics, with most concerns limited to people who have a known sulfite allergy or very reactive skin. As with any new product, doing a quick patch test is a smart habit to spot any personal sensitivity before full use.

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