Sodium Hexeth-4 Carboxylate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Sodium Hexeth-4 Carboxylate?

Sodium Hexeth-4 Carboxylate is a synthetic ingredient made by linking hexyl alcohol with four units of ethylene oxide, then attaching a carboxylic acid group and neutralizing it with sodium. The result is a water-loving powder or liquid that dissolves easily in water. It first appeared in the 1960s when chemists looked for milder substitutes for traditional soaps. Because it balances oil and water, brands soon blended it into everyday skin and hair formulas. Manufacturing starts with plant-derived or petroleum-based hexyl alcohol, which is ethoxylated, reacted with chloroacetic acid to add the carboxylate part, then treated with sodium hydroxide to create the final salt. Today you’ll spot it in facial cleansers, micellar waters, shampoos, body washes, toners, lightweight moisturizers and clear serums where a gentle cleansing boost is needed.

Sodium Hexeth-4 Carboxylate’s Cosmetic Benefits/Uses

This ingredient brings more than one helpful role to a formula

  • Cleansing: Works as a mild surfactant that lifts dirt, excess oil and makeup without stripping the skin or hair so products feel gentle yet effective
  • Hydrotrope: Helps water mix with oily or waxy ingredients, keeping the formula clear and stable while allowing brands to use less overall surfactant which can improve skin comfort

Who Can Use Sodium Hexeth-4 Carboxylate

Sodium Hexeth-4 Carboxylate is generally suitable for normal, oily and combination skin because it removes excess sebum without overly stripping. Sensitive skin often tolerates it too thanks to its mild nature though very dry or compromised skin might prefer richer cleansers since repeated use could leave them feeling tight.

The material is synthetically produced from plant derived or petroleum based feedstocks and contains no animal derivatives so it is suitable for vegans and vegetarians.

No specific data suggest any risk for pregnant or breastfeeding women when the ingredient is used in rinse off or leave on cosmetics at customary levels. This is not medical advice and anyone who is pregnant or nursing should have a doctor review any product they plan to use just to be safe.

Sodium Hexeth-4 Carboxylate does not increase photosensitivity and does not require special sun precautions beyond daily sunscreen habits.

Potential Side Effects/Adverse Reactions

Responses to topical Sodium Hexeth-4 Carboxylate differ from person to person. The points below outline potential side effects yet most people will not experience them when the ingredient is properly formulated and used as directed.

  • Transient stinging or tingling when applied to broken or freshly exfoliated skin
  • Mild dryness if used too frequently on very dry skin types
  • Redness or itching in individuals with an existing surfactant sensitivity
  • Watery eyes or irritation if the cleanser accidentally gets into the eye area
  • Rare allergic contact dermatitis marked by persistent rash or swelling

If you experience any of these reactions discontinue use and seek advice from a healthcare professional.

Comedogenic Rating

Rating: 0/5 (non comedogenic)

Sodium Hexeth-4 Carboxylate is entirely water soluble and typically used in rinse off cleansers at low levels so it does not linger on the skin or build up inside pores. Lacking heavy oils or waxes, it has virtually no potential to block follicles or encourage blackheads.

This makes it a sound option for those who are acne prone or experience frequent breakouts.

No research links the ingredient to fungal acne and it contains no fatty acids that feed Malassezia yeast, adding further reassurance for users with that concern.

Summary

Sodium Hexeth-4 Carboxylate acts as a gentle cleanser and hydrotrope. Its ethoxylated chain grabs on to oil and grime so water can whisk them away, while the charged carboxylate end keeps watery and oily components blended for a clear stable formula.

Although not a headline ingredient, it quietly features in many mild face washes, micellar waters, body cleansers and clear shampoos where a soft touch is valued.

Overall safety is high with minimal irritation risk and no known systemic issues. Still, skin is personal so a quick patch test when trying a new product containing this ingredient is the sensible move.

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