Sodium Metaphosphate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
Share:
Inside this article:

We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Sodium Metaphosphate?

Sodium metaphosphate is a salt formed from sodium and metaphosphoric acid. It appears as a white, water-soluble powder with no smell and a slightly alkaline taste. In nature small amounts occur in certain mineral deposits, but the material used in cosmetics is made in a lab for purity and consistency. Manufacturers produce it by heating sodium dihydrogen phosphate until the molecules link together into long chains called polyphosphates, then milling the cooled solid into fine powder.

The beauty industry first showed interest in the 1950s when researchers noticed how well this salt softened hard water in cleaning products. Over time formulators discovered that its ability to control pH and bind metal ions also helped preserve color, texture and stability in creams and gels. Today it is used worldwide in both mass-market and professional lines.

You will most often spot sodium metaphosphate in toothpaste, mouthwash and whitening strips, but it also turns up in rinse-off cleansers, sheet masks, clay masks, exfoliating powders, anti-aging serums and some lightweight moisturizers where formulators want a stable product that feels fresh on the skin.

Sodium Metaphosphate’s Cosmetic Benefits/Uses

Below are the main ways this multitasking ingredient supports a formula

  • Buffering: Helps keep the product’s pH within a skin-friendly range so the formula stays gentle and effective throughout its shelf life
  • Chelating: Binds to trace metals that can cause discoloration, rancidity or texture changes which means the product looks and feels the same from the first application to the last
  • Oral Care: Breaks up dental plaque, loosens surface stains and softens hard water so toothpaste or mouthwash foams and cleans better giving a fresher feel in the mouth

Who Can Use Sodium Metaphosphate

Sodium metaphosphate is gentle and water soluble so it suits most skin types including oily, dry, combination and normal. Its pH buffering keeps formulas mild which makes it a reasonable choice even for sensitive skin, though anyone with very reactive or broken skin should watch for irritation the first few uses.

Because this salt is made from mineral sources in a lab with no animal by products it is considered suitable for vegans and vegetarians.

Current research has not flagged any specific risks for people who are pregnant or breastfeeding when the ingredient is used on skin or teeth, yet out of caution it is best to show any product containing it to a doctor or midwife before regular use. This is general information, not medical advice.

Sodium metaphosphate does not make skin more prone to sunburn and it has no known effect on tanning products or sunscreen performance.

Potential Side Effects/Adverse Reactions

Responses to topical sodium metaphosphate differ from person to person. Below is a list of potential side effects, though most people will not notice any of these when the ingredient is used at normal cosmetic levels.

  • Mild stinging or redness on very sensitive skin
  • Localized dryness if used in a high concentration wash off powder
  • Temporary taste disturbance when used in oral care products
  • Eye irritation if the powder or foam accidentally gets into the eyes
  • Rare allergic contact dermatitis marked by itching or rash

If any of these effects occur stop using the product and seek advice from a healthcare professional.

Comedogenic Rating

Comedogenic rating: 0/5

Sodium metaphosphate is a small water-soluble salt that dissolves completely in the watery phase of a formula and rinses away easily. It contains no oils or waxes that could block pores so it earns a zero on the comedogenic scale.

That means it is generally considered suitable for people who are prone to acne or frequent breakouts.

Because it is typically used at low levels and often found in rinse-off or very light leave-on products there is little chance of it building up on the skin or mingling with sebum.

Summary

Sodium metaphosphate acts as a pH buffer, a chelator and an oral care aid. It keeps formulas at a skin-friendly acidity, ties up metal ions that might discolor or destabilize products and softens water so cleansers and toothpastes work more effectively.

It is a quiet workhorse that shows up most in toothpastes and mouthwashes and pops into cleansers masks and some serums when formulators need dependable stability. It is not a buzzword ingredient but professionals appreciate the backstage support it provides.

Safety reviews rate it low risk for topical use and most users experience no issues. Skin can still be unpredictable so patch test any new product that contains sodium metaphosphate before making it a regular part of your routine.

Was this article helpful?
More from Glooshi:
ADVERTISEMENT
Get all our top headlines in beauty.
Delivered right to your inbox each week. Zero spam, all goodness, opt-out at anytime.
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Get the latest beauty news, top product recommendations & brand-exclusive discount codes direct to your inbox.
Send good feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Send bad feedback:

All feedback is greatly appreciated, anonymous, and will be used to improve the quality of our articles.

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Search