Sodium Naphthalenesulfonate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Sodium Naphthalenesulfonate?

Sodium naphthalenesulfonate is the sodium salt form of 2-naphthalenesulfonic acid. It comes from naphthalene, a substance originally sourced from coal tar that is now more often produced from petroleum. Chemically it is a white to off-white powder that dissolves easily in water, giving it useful surface-active properties.

The cosmetic world first noticed this ingredient in the mid-20th century when formulators looked for mild yet effective cleansing agents that could also improve the way other ingredients mix. Over time its reliability, ease of manufacture and low cost secured its place in many everyday products.

Manufacturing starts with naphthalene, which is sulfonated to add a sulfonic acid group. Neutralizing this acid with sodium hydroxide converts it to the sodium salt, yielding sodium naphthalenesulfonate. The final material is filtered, dried and milled to a fine powder before quality checks clear it for cosmetic use.

You will most often spot it in facial cleansers, body washes, shampoos, liquid soaps and some clay or sheet masks. It can also show up in toners, makeup removers and light lotions where formulators need a helper that keeps the formula clear and stable.

Sodium Naphthalenesulfonate’s Cosmetic Benefits/Uses

This ingredient plays more than one role in personal care formulas

  • Cleansing: It helps lift dirt, oil and daily build-up from skin or hair so they can be rinsed away with water. Because it is milder than many classic detergents it supports a gentle cleanse that leaves the skin feeling fresh rather than stripped
  • Hydrotrope: As a hydrotrope it improves the solubility of other ingredients, keeping fragrances, essential oils and plant extracts evenly dispersed. This prevents cloudiness or separation so the product stays clear, consistent and pleasant to use

Who Can Use Sodium Naphthalenesulfonate

Most skin types can tolerate sodium naphthalenesulfonate because it cleanses without a harsh stripping effect. Normal, oily and combination skin usually find it comfortable, while dry or very sensitive skin may want to pair it with richer moisturizers to avoid a tight feeling after washing. People dealing with inflammatory skin concerns like eczema or rosacea should check with a dermatologist if they notice any increase in irritation after use.

The ingredient is synthetic and not sourced from animals, making it suitable for vegans and vegetarians. It is also free of animal by-products during typical manufacturing.

No evidence currently links sodium naphthalenesulfonate to problems during pregnancy or breastfeeding when used in rinse-off or leave-on cosmetics. That said this is not medical advice. Anyone who is pregnant or nursing should review any skincare product with a qualified healthcare professional to stay on the safe side.

Sodium naphthalenesulfonate does not increase photosensitivity, so it will not make skin more prone to sunburn. Sunscreen use is still advised for daily UV protection.

Potential Side Effects/Adverse Reactions

Reactions to topical sodium naphthalenesulfonate differ from person to person. The points below list potential side effects, though most users will not experience them when the ingredient is properly formulated and used as directed.

  • Skin dryness
  • Mild irritation or stinging on compromised skin
  • Redness or itching in those with fragrance or preservative sensitivities if these are also present in the formula
  • Eye discomfort if the product accidentally gets into the eyes

If any unwanted reaction occurs stop using the product and consult a healthcare professional for guidance.

Comedogenic Rating

Rating: 0/5

Sodium naphthalenesulfonate is highly water soluble and does not leave an oily film on the skin, so it has no tendency to block pores. Because it functions mainly as a cleansing agent and solubility booster, it quickly rinses away without lingering on the surface.

Suitable for acne-prone or breakout-prone skin.

No studies or user reports link this ingredient to increased blackheads, whiteheads or cystic acne. Its performance is similar to other low-residue surfactants often labelled non-comedogenic.

Summary

Sodium naphthalenesulfonate works as a gentle cleanser and as a hydrotrope that keeps tricky oils, fragrances and extracts dissolved so a formula stays clear and uniform. Its ability to lift away dirt while boosting solubility makes it a quiet multitasker in products like facial cleansers, toners, shampoos and sheet masks.

While not the star of marketing campaigns, it is a reliable backstage player that formulators reach for when they need an affordable ingredient that does its job without fuss.

Current safety data shows a low risk of irritation or clogging. Most people can use products containing sodium naphthalenesulfonate with confidence, yet it is always smart to patch test any new skincare item before full use just to be cautious.

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