Stearyl/Octyldodecyl Citrate Crosspolymer: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Stearyl/Octyldodecyl Citrate Crosspolymer?

Stearyl/Octyldodecyl Citrate Crosspolymer is a synthetic polymer created by linking stearyl alcohol, octyldodecanol and citric acid with 1,3-propanediol. The fatty alcohol portions are usually sourced from plant oils like coconut or palm while citric acid comes from fermented sugar crops, giving the material a largely renewable origin. During production the raw fatty alcohols are first esterified with citric acid, then the resulting molecules are crosslinked through controlled heating with 1,3-propanediol to form a three-dimensional network. This process transforms otherwise oily ingredients into a solid powder that disperses smoothly in water or oil phases.

The polymer began appearing in cosmetics in the early 2010s when formulators looked for plant-derived texturizers that could boost moisture without leaving a greasy feel. Today it is added to lightweight moisturizers, hydrating serums, sheet masks, silicone-free primers, stick foundations and even some sunscreens where it improves skin feel and water retention.

Stearyl/Octyldodecyl Citrate Crosspolymer’s Cosmetic Benefits/Uses

In skincare and makeup formulas this ingredient plays a single but valuable role.

As a humectant it attracts and holds water at the skin surface, helping products deliver lasting hydration. By binding moisture the polymer supports a plumper smoother look, reduces the appearance of fine lines caused by dryness and enhances the spreadability of creams or gels. It also stabilizes emulsions, keeping oil and water components evenly blended for a consistent texture throughout the product’s shelf life.

Who Can Use Stearyl/Octyldodecyl Citrate Crosspolymer

This humectant is gentle enough for most skin types. Dry or dehydrated skin benefits from its water-binding ability while oily or combination skin appreciates that it hydrates without an oily residue. Sensitive skin generally tolerates the polymer well because it is chemically stable and free of common allergens. There are no known concerns for mature or teen skin either.

The fatty alcohols are sourced from plants and the other building blocks come from fermented sugars so the final material contains no animal-derived components, making it suitable for vegans and vegetarians.

Current safety data shows no reproductive or developmental toxicity, so products containing Stearyl/Octyldodecyl Citrate Crosspolymer are considered safe for women who are pregnant or breastfeeding. This is not medical advice and anyone expecting or nursing should run all skincare choices past a qualified healthcare professional just to be safe.

The ingredient does not increase photosensitivity, so it will not make skin more prone to sunburn. It also plays well with common actives like retinol, vitamin C and acids, offering flexible use in multi-step routines.

Potential Side Effects/Adverse Reactions

Responses to topical ingredients differ between individuals. The following points outline potential side effects of Stearyl/Octyldodecyl Citrate Crosspolymer, though they are considered rare when the ingredient is used at standard cosmetic levels.

  • Mild skin irritation such as transient stinging or burning
  • Redness or flushing in highly reactive skin
  • Allergic contact dermatitis in people sensitive to fatty alcohol derivatives
  • Product pilling if applied in thick layers over silicone-rich formulas

If any discomfort or skin reaction occurs stop using the product and consult a healthcare professional.

Comedogenic Rating

Rating: 1/5

Stearyl/Octyldodecyl Citrate Crosspolymer scores a low 1 because the fatty alcohol chains are locked into a large three-dimensional network that sits on skin rather than melting into pores. The powdery texture leaves little oily residue and is used at modest levels in formulas, so the chance of pore blockage is slim.

With this rating the ingredient is generally fine for people who tend to break out, though the overall formula and personal skin behavior always make a difference.

As with any fatty alcohol-based material, higher use levels in rich creams could bump up the clogging risk a bit, but current product concentrations stay well below that threshold.

Summary

Stearyl/Octyldodecyl Citrate Crosspolymer is a plant-derived humectant that binds water to the skin, smooths texture and helps keep emulsions stable. Its crosslinked structure lets it deliver moisture without a greasy feel, making it handy in lightweight lotions, primers and even color cosmetics.

It is not a headline superstar like hyaluronic acid, yet formulators appreciate its clean feel and renewable origin so its presence has grown quietly over the past decade.

Safety studies show a very low irritation profile, no sensitization and no reproductive concerns, so most people can use it with confidence. As with any new skincare ingredient, do a quick patch test when trying a fresh product just to be safe.

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