Trioleyl Phosphate: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Trioleyl Phosphate?

Trioleyl phosphate is an oily liquid derived from oleic acid, the same fatty acid that gives olive oil much of its skin-loving reputation. By linking three oleyl groups to a single phosphate core, chemists create a molecule that feels silky yet stays put on skin. It first appeared in industrial settings as a plasticiser that kept materials flexible, and formulators soon noticed its smooth, cushiony texture worked just as well in creams and lotions. Today it is produced through controlled esterification, a process that bonds purified oleyl alcohol with phosphate under heat and catalytic conditions, followed by filtration to remove any residues.

You are most likely to spot trioleyl phosphate in rich moisturizers, barrier-repair balms, overnight masks, anti-aging creams and certain long-wear makeup bases where a soft, pliable finish is desirable.

Trioleyl Phosphate’s Cosmetic Benefits/Uses

In skin care and makeup trioleyl phosphate lends several helpful qualities:

  • Plasticiser – keeps formulas flexible so they spread evenly and resist cracking or flaking, which is especially useful in long-wear foundations and cream eyeshadows
  • Skin Conditioning – forms a light, breathable film that softens rough patches and supports the skin’s natural moisture barrier
  • Emollient – fills in microscopic gaps between skin cells to leave the surface smooth and supple while adding a pleasant slip during application

Who Can Use Trioleyl Phosphate

Trioleyl phosphate is generally well tolerated by most skin types. Dry and mature skin often benefits the most thanks to its emollient cushion while normal and combination skin can enjoy the added softness without feeling greasy. Oily or highly acne-prone skin may want to use it sparingly since richer lipids sometimes feel too occlusive for those who struggle with frequent breakouts.

The ingredient is created from oleic acid sourced from plant oils so it is suitable for vegans and vegetarians. No animal-derived steps are required during manufacturing.

Current research has not flagged trioleyl phosphate as a concern for pregnancy or breastfeeding. That said this is not medical advice and anyone who is pregnant or nursing should ask their healthcare provider before introducing new skincare products just to be safe.

Trioleyl phosphate does not increase photosensitivity so there is no extra sun-care precaution beyond the daily SPF experts already recommend. It also has no known conflicts with common actives like retinol or vitamin C making it an easy add-on in most routines.

Potential Side Effects/Adverse Reactions

Individual responses to topical trioleyl phosphate can vary. The points below cover potential reactions but most people will not notice any drawbacks when the ingredient is formulated and used correctly.

  • Mild skin irritation
  • Redness or warmth in very sensitive skin
  • Clogged pores in those already prone to congestion
  • Allergic contact dermatitis in rare cases

If you experience any discomfort rash or prolonged redness stop using the product and consult a qualified healthcare professional.

Comedogenic Rating

Rating: 2 / 5

Trioleyl phosphate is derived from oleic acid, which can be mildly pore clogging, but esterifying it with phosphate reduces its stickiness and makes it less likely to build up inside follicles. Most users will not notice extra breakouts, yet those with very oily or congestion-prone skin might still find it a bit heavy when used in high concentrations. Overall it falls on the lower end of the comedogenic scale, so it can be used by acne-prone individuals who monitor how their skin responds.

Because trioleyl phosphate stays fluid at skin temperature it tends to spread out rather than pool in pores, which also lowers clogging potential compared with thicker butters or waxes.

Summary

Trioleyl phosphate acts as a plasticiser, skin-conditioning agent and emollient. Its triple oleyl tails create slip and flexibility in creams and makeup while the phosphate core anchors a light film on the skin surface to smooth and soften rough patches. By filling microscopic gaps between cells it reinforces the moisture barrier and leaves a silky afterfeel.

The ingredient is a quiet workhorse rather than a headline superstar. It shows up most often in richer moisturizers, barrier balms and long-wear color cosmetics where a cushioned finish is prized, but it is not as widely talked about as hyaluronic acid or niacinamide.

Current safety data classifies trioleyl phosphate as low risk with only rare irritation or allergy reports. As with any new product it is wise to perform a small patch test before full-face use to ensure personal compatibility.

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