Undecylenoyl Hydrolyzed Collagen: What Is It, Cosmetic Uses, Benefits & Side Effects

Curious about this ingredient? In this article we're explaining exactly what it is and why it's used within cosmetic formulations.
Updated on: June 30, 2025
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We verify all information on this page using publicly available nomenclature standards from The Personal Care Products Council (PCPC), the European Commission's CosIng database and documentation provided directly by ingredient manufacturers. Our analysis is based on technical data from these sources to ensure accuracy and reliability.

What Is Undecylenoyl Hydrolyzed Collagen?

Undecylenoyl Hydrolyzed Collagen is a modified form of collagen in which short collagen peptides have been chemically linked to undecylenic acid, a fatty acid obtained from castor oil. The base collagen usually comes from bovine hides or marine fish skin, then it is hydrolyzed into low-molecular-weight peptides that dissolve easily in water. These peptides are reacted with undecylenoyl chloride under controlled conditions to attach the lipid-like undecylenoyl group, creating an amphiphilic ingredient that blends the water-loving nature of peptides with the oil-affinity of fatty chains.

Collagen derivatives began appearing in cosmetics in the 1950s as chemists looked for ways to boost moisture retention and softness in skin creams. The undecylenoyl version emerged decades later when formulators discovered that adding a fatty chain could improve the peptide’s ability to stick to hair and skin while also giving it mild cleansing and antimicrobial properties.

Today Undecylenoyl Hydrolyzed Collagen is found in a wide range of products: leave-on and rinse-off hair conditioners, anti-frizz shampoos, facial and sheet masks, anti-aging serums, lightweight moisturizers, micellar waters, gentle facial cleansers and after-shave balms. Its versatility lets brands use one ingredient to deliver conditioning, cleansing and feel-good texture all at once.

Undecylenoyl Hydrolyzed Collagen’s Cosmetic Benefits/Uses

This multi-purpose ingredient supports several useful roles in modern formulations

  • Antistatic: Forms a thin protein-rich film on hair that helps neutralize static buildup so strands stay smoother and easier to style
  • Cleansing: The undecylenoyl group provides mild surfactant action that lifts away surface oil and dirt without stripping moisture, ideal for gentle shampoos and face washes
  • Hair conditioning: Positively charged peptide fragments bind to damaged areas of the cuticle, enhancing softness, manageability and shine while reducing breakage
  • Skin conditioning: Creates a breathable film that holds water at the surface, leaving skin feeling hydrated, supple and lightly tightened after application

Who Can Use Undecylenoyl Hydrolyzed Collagen

Because it is water soluble and forms a breathable film, Undecylenoyl Hydrolyzed Collagen suits most skin types including dry, normal, combination and mildly sensitive skin. The lightweight peptides lock in moisture without leaving a greasy feel so even those prone to clogged pores usually tolerate it well. If your skin is extremely oily the film forming action can occasionally feel too coating which is why ultra-light gel formulas may be preferred.

The ingredient is not vegan or vegetarian friendly in its usual form because the collagen portion comes from animal sources such as bovine hide or marine fish. Some brands highlight fish-only collagen which can be acceptable for pescatarians but still does not meet vegan standards.

Topical use during pregnancy or while breastfeeding is generally considered low risk because the peptides sit on the surface and do not reach the bloodstream in meaningful amounts. This is not medical advice and anyone who is pregnant or nursing should show the full product ingredient list to a qualified health professional before use.

Undecylenoyl Hydrolyzed Collagen does not make skin more sensitive to the sun so there is no added need for extra sun precautions beyond a daily broad-spectrum sunscreen. It also plays well with most common actives like niacinamide and hyaluronic acid making it easy to slot into an existing routine.

Potential Side Effects/Adverse Reactions

Responses to any cosmetic ingredient differ from person to person. The points below outline possible side effects of Undecylenoyl Hydrolyzed Collagen but most people will not experience them when using a well-formulated product.

  • Mild skin irritation – a small number of users may notice temporary redness or tingling especially if the formula includes other strong actives
  • Allergic contact dermatitis – rare but possible in individuals allergic to animal proteins or fish byproducts
  • Eye stinging – can occur if a shampoo or cleanser containing the ingredient splashes into the eyes
  • Product buildup on hair – heavy leave-on doses may weigh down very fine hair making it appear limp
  • Unwanted odor – marine sourced versions can carry a slight fish scent that some users find unpleasant

If you notice any of these reactions stop using the product and seek guidance from a healthcare professional or dermatologist.

Comedogenic Rating

Rating: 1 / 5

Undecylenoyl Hydrolyzed Collagen is largely water soluble and forms a very light film so it does not clog pores the way heavier oils or waxes can. The undecylenoyl chain does add a small fatty component which is why it is not rated a perfect zero, but its overall molecular size plus its amphiphilic nature keep the risk of pore blockage low.

Suitable for acne-prone or breakout-prone skin in most cases.

Formulas that pair this ingredient with rich butters or comedogenic oils could raise the overall pore-clogging potential so always consider the full ingredient list.

Summary

Undecylenoyl Hydrolyzed Collagen delivers four main benefits: it conditions skin by forming a moisture-holding peptide film, conditions hair by bonding to damaged cuticles for softness and shine, reduces static on strands and offers gentle cleansing thanks to its fatty undecylenoyl tail. The peptide portion loves water while the fatty chain loves oil which lets the ingredient sit at the interface of both and perform these multiple jobs at once.

It is not as famous as hyaluronic acid or niacinamide but formulators value it for its versatility in lightweight serums, conditioners and mild cleansers so its presence on labels is slowly growing.

Topical use is considered low risk with irritation or allergies appearing rarely. As with any new cosmetic it is wise to do a quick patch test before adding a product containing Undecylenoyl Hydrolyzed Collagen to your daily routine.

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